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Acta Chimica Sinica ›› 1996, Vol. 54 ›› Issue (3): 271-275. Previous Articles Next Articles
Original Articles
展树中;孟庆金;戴安邦
发布日期:
ZHAN SHUZHONG;MENG QINGJIN;DAI ANBANG
Published:
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Four kinds of new cyano-bridge complexes have been prepared and characterized by elemental analysis, IR spectra, UV-Vis spectra, Luminescent spectra and electrochemical techniques. The formation of cyanide bridge is evident from the IR and UV-Vis spectra by appearance of (ν~C≡~N) shifts and changes in λ~m~a~x with respect to the mononuclear parent complex [Fe(CN)]^4^- and [CoLm]^3^+, respectively. The complexes studied are interesting as models for the design of energy conversion schemes.
Key words: INFRARED SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, IRON COMPLEX, COBALT COMPLEX, POTASSIUM FERROCYANIDE, FLUOROSPECTROPHOTOMETRY, CYCLOVOLTAMGRAPH
CLC Number:
O611.662
ZHAN SHUZHONG;MENG QINGJIN;DAI ANBANG. Synthesis and properties of cyano-bridged complexes [LmCo^Ⅲ-μ-NC-Fe^Ⅱ(CN)~5]^-[J]. Acta Chimica Sinica, 1996, 54(3): 271-275.
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