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Acta Chimica Sinica ›› 1994, Vol. 52 ›› Issue (2): 171-175. Previous Articles Next Articles
Original Articles
廖代正;石娟;姜宗慧;阎世平;王耕霖
发布日期:
LIAO DAIZHENG;SHI JUAN;JIANG ZONGHUI;YAN SHIPING;WANG GENGLIN
Published:
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Oxalate-bridged [Cu2(phen)2Cr(OX)3]NO3 and [Cu2(Mebpy)2Cr(OX)3]NO3 (H2OX = oxalic acid, phen = 1,10-phenanthroline, Mebpy = 4,4-dimethyl-2,2-bipyridyl) were prepared and characterized. The temperature dependence of magnetic susceptibilities of complexes was studied in 4.2-300 K range, and the exchange integral Jcu-Cr is 35.18 cm-1 for [Cu2(Mebpy)2Cr(OX)3]NO3 and 30.24 cm-1 for [Cu2(phen)2Cr(OX)3]NO3 on the base of spin Hamiltonian H = -2J (SCu1譙Cr + SCu2譙Cr). The results are commensurate with ferromagnetic interactions between the Cu(II) and Cr(III) ions.
Key words: COPPER COMPLEX, OXALATO COMPLEX, PHENANTHROLINE P, BIPYRIDINE P, CHROMIUM COMPLEX
CLC Number:
O611.662
LIAO DAIZHENG;SHI JUAN;JIANG ZONGHUI;YAN SHIPING;WANG GENGLIN. Ferromagenetic oxalate-bridged trinuclear Cu(Ⅱ)-Cr(Ⅲ)-Cu(Ⅱ) complexes[J]. Acta Chimica Sinica, 1994, 52(2): 171-175.
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