Acta Chimica Sinica ›› 2007, Vol. 65 ›› Issue (17): 1807-1813. Previous Articles     Next Articles

Original Articles

N80油套管钢应力状态下的CO2腐蚀行为研究

李党国*,1,2, 冯耀荣2, 白真权2, 郑茂盛1   

  1. (1西安交通大学材料科学与工程学院 西安 710049)
    (2中国石油天然气集团公司管材研究所 西安 710065)
  • 投稿日期:2006-11-13 修回日期:2007-03-07 发布日期:2007-09-14
  • 通讯作者: 李党国

Investigation on CO2 Corrosion Behaviors of N80 Tubing Steel Under Stress Conditions

LI Dang-Guo*,1,2; FENG Yao-Rong2; BAI Zhen-Quan2; ZHENG Mao-Sheng1   

  1. (1 School of Material Science and Engineering, Xi'an Jiaotong University, Xi'an 710049)
    (2 Tubular Goods Research Center of China National Petroleum Corporation, Xi'an 710065)
  • Received:2006-11-13 Revised:2007-03-07 Published:2007-09-14
  • Contact: LI Dang-Guo

The CO2 corrosion behavior of N80 steel in stratum water with saturated CO2 under tension, compression and bending stress conditions, was investigated by electrochemical impedance spectra. The results showed that the anodic impedance spectra under the three stress conditions all consisted of three time-constants, i.e., the capacitance at high frequency, inductance at middle frequency and capacitance at low frequency, among which the frequency at high frequency and the capacitance of the double-layer were related to the transfer impedance, the dissolution of N80 steel contributed to the inductance, and the capacitance at low frequency was corresponding to the formation of corrosion film on N80 surface. With the stress increment, the inductance increased, and the capacitance at low frequency decreased, meaning that the anodic reaction rate increased under the stress conditions. The cathodic impedances under the three stress conditions all consisted of capacitance at high frequency, Warburg im-pedance and capacitance at middle and low frequencies, and with the increment of strain under the three stress conditions, the Warburg impedance increased, while the reaction impedance and the capacitance of double-layer decreased, meaning that the CO2 corrosion may be accelerated when N80 steel is under the stress conditions.

Key words: N80 steel, electrochemical impedance spectra, CO2 corrosion, stress condition