share
Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (7): 677-682. Previous Articles Next Articles
Original Articles
姚克敏;李冬成;沈联芳;袁汉珍
发布日期:
YAO KEMIN;LI DONGCHENG;SHEN LIANFANG;YUAN HANZHEN
Published:
Share
A new Schiff base (H3L) was obtained through the reaction of 2,4-dihydroxybenzaldehyde with anthranilic acid in alcohol [Ln(H2L)2NO3] (Ln = La, Pr, Nd, Sm. Gd, Dy, Ho, Er, Yb), which were not reported previously, were synthesized using an improved method and characterized by elemental anal., molar conductivity, TG-DTA, IR, UV and NMR spectra. The ligand, which acts as tridentate in the complexes, forms a double 6-membered ring structure with Ln(III). These complexs can be used as a new catalyst in the polymerisation of Me methacrylate.
Key words: ULTRAVIOLET SPECTROPHOTOMETRY, METHYLMETHACRYLATE, INFRARED SPECTROPHOTOMETRY, NMR SPECTROMETRY, BENZENECARBOXYLIC ACID P, YTTRIUM COMPLEX, HOLMIUM COMPLEX, THERMOGRAVIMETRY, YTTERBIUM COMPLEX, DIFFERENTIAL THERMAL ANALYSIS
CLC Number:
O611.662
YAO KEMIN;LI DONGCHENG;SHEN LIANFANG;YUAN HANZHEN. Synthesis and characterization of new lanthanide complexes with N-(2,4-dihydroxybenzalidene)-anthranilic acid and their catalytic activity[J]. Acta Chimica Sinica, 1993, 51(7): 677-682.
Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks