Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (7): 677-682. Previous Articles     Next Articles

Original Articles

镧系与邻氨基苯甲酸型Schiff碱配合物的合成、表征及催化活性

姚克敏;李冬成;沈联芳;袁汉珍   

  1. 浙江大学化学系;中国科学院波谱与原子分子物理开放实验室
  • 发布日期:1993-07-15

Synthesis and characterization of new lanthanide complexes with N-(2,4-dihydroxybenzalidene)-anthranilic acid and their catalytic activity

YAO KEMIN;LI DONGCHENG;SHEN LIANFANG;YUAN HANZHEN   

  • Published:1993-07-15

A new Schiff base (H3L) was obtained through the reaction of 2,4-dihydroxybenzaldehyde with anthranilic acid in alcohol [Ln(H2L)2NO3] (Ln = La, Pr, Nd, Sm. Gd, Dy, Ho, Er, Yb), which were not reported previously, were synthesized using an improved method and characterized by elemental anal., molar conductivity, TG-DTA, IR, UV and NMR spectra. The ligand, which acts as tridentate in the complexes, forms a double 6-membered ring structure with Ln(III). These complexs can be used as a new catalyst in the polymerisation of Me methacrylate.

Key words: ULTRAVIOLET SPECTROPHOTOMETRY, METHYLMETHACRYLATE, INFRARED SPECTROPHOTOMETRY, NMR SPECTROMETRY, BENZENECARBOXYLIC ACID P, YTTRIUM COMPLEX, HOLMIUM COMPLEX, THERMOGRAVIMETRY, YTTERBIUM COMPLEX, DIFFERENTIAL THERMAL ANALYSIS

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