Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (12): 1178-1181. Previous Articles     Next Articles

Original Articles

十一钨铌杂多阴离子的合成

赵由才;谢高阳;顾翼东   

  1. 复旦大学化学系
  • 发布日期:1992-12-15

The synthesis of [C~4H~9)N]~nK~7-nNbW~11O~40H~2 complex(n=5,6)

ZHAO YOUCAI;XIE GAOYANG;GU YIDONG   

  • Published:1992-12-15

KNbO3 and powdery white tungstic acid in aqueous solution The structure of the anion may be proposed reasonably to be similar to that of [W12O40H2]6-, resulting from substituting of 1 WO6 group by 1 NbO6 group and giving [NbW11O40H2]7- according to the extreme similarity of IR and Raman spectra of these 2 different anions.

Key words: INFRARED SPECTROPHOTOMETRY, HETEROPOLYACID, POTASSIUM COMPOUNDS, NIOBATE P, TUNGSTATE P, WHITE TUNGESTIC ACID, RAMAN SPECTROMETRY

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