Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (1): 18-22. Previous Articles     Next Articles

Original Articles

PS自由基的形成及动力学研究

郭敬忠;王海庆;顾月姝;刘传朴;印永嘉;曹德兆;李书涛   

  1. 山东大学化学系
  • 发布日期:1993-01-15

Formation of excited PS fragments and its kinetic study

GUO JINGZHONG;WANG HAIQING;GU YUEZHU;LIU CHUANPU;YING YONGJIA;CAO DEZHAO;LI SHUDAO   

  • Published:1993-01-15

The energy transfer reaction of metastable He(23S) and Ne(3P0.2) with PSCl3 was investigated. Emission spectra of PS(B ?X) and PS(C ?X) were observed Based on the spectra of excited fragments the authors estimated the formation rate constants and vibrational population of PS(B) and PS(C). The reaction mechanisms are discussed.

Key words: LUMINESCENT SPECTRA, REACTION KINETICS, METASTABLE STATES, FREE RADICALS

CLC Number: