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Acta Chimica Sinica ›› 2009, Vol. 67 ›› Issue (16): 1897-1902. Previous Articles     Next Articles

Original Articles

酚氧基联烯基醚单体的原子转移自由基聚合研究

张晓鸿a 袁 丽a 杨 东a 胡建华*,a 陈晓枫b 王 利b

  

  1. (a聚合物分子工程教育部重点实验室 复旦大学先进材料实验室 复旦大学高分子科学系 上海 200433)
    (b复旦大学分析测试中心 上海 200433)

  • 投稿日期:2009-07-06 修回日期:2009-07-22 发布日期:2009-08-28
  • 通讯作者: 胡建华

Studies on Atom Transfer Radical Polymerization of Phenoxyallene

Zhang, Xiaohong a Yuan, Li a Yang, Dong a Hu, Jianhua *,a
Chen, Xiaofeng b Wang, Li b

  

  1. (a Key Laboratory of Molecular Engineering of Polymers Ministry of Education, Laboratory of Advanced Materials,
    Department of Macromolecular Science, Fudan University, Shanghai 200433)
    (b Center of Analysis and Measurement, Fudan University, Shanghai 200433)
  • Received:2009-07-06 Revised:2009-07-22 Published:2009-08-28
  • Contact: Hu Jian-Hua

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Atom transfer radical polymerizations (ATRP) of phenoxyallene (POA) and p-tert-butyl phenoxyallene (t-BuPOA) were studied using different initiators and ligands. It was found that the polymerization of POA followed the mechanism of ATRP both in the systems of methyl 2-bromopropanoate/CuBr/4,4’-diheptyl-2,2’-bipyridine (2-MBP/CuBr/dHbpy) and p-toluene sulfonyl chloride/CuBr/tris-[2-(dimethylamino)ethyl]amine (p-TsCl/CuBr/Me6TREN).

Key words: phenoxyallene, atom transfer radical polymerization (ATRP), controlled radical polymerization