Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (7): 632-636. Previous Articles     Next Articles

Original Articles

二(乙酰丙酮根)合铜(Ⅱ)热分解动力学研究

连志睿;金忠;秦启宗   

  1. 复旦大学激光化学研究室
  • 发布日期:1992-07-15

Kinetics on the thermal deposition of copper(Ⅱ)acetylacetonate

LIAN ZHIRUI;JIN ZHONG;QIN QIZONG   

  • Published:1992-07-15

The kinetics of the thermal decomposition of Cu(acac)2 (Hacac = acetylacetone) on quartz substrate was studied. Heating of the substrate was accomplished with a CO2 laser beam. The deposition of a copper film by this process was dependent on the laser intensity and an intensity threshold was observed above which linear kinetics were determine The decomposition of Cu(acac)2 was first order. The rate controlling step was surface reaction on the substrate at low laser intensity and transport of precursor mols. at high laser intensity.

Key words: SURFACES, COPPER COMPLEX, QUARTZ, SEDIMENTATION, THERMAL DECOMPOSITION, ACETOPREPANONE, KINETIC STUDY

CLC Number: