Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (7): 691-697. Previous Articles     Next Articles

Original Articles

^15N标记的二(2-羟基苯乙酮肟)^63Cu(Ⅱ) 配合物的ESR和配体核的ENDOR研究

陈德余;徐元植;宫本量;大庭裕;岩泉正基;陈耀焕;周澄明   

  1. 浙江大学化学系;日本东北大学非水溶液化学研究所;中国科学院上海有机化学研究所
  • 发布日期:1992-07-15

Studies on ESR spectra and ENDOR spectra of ^15N label bis (2- hydroxyacetophenone oxime)-^63 Cu(Ⅱ) complex

CHEN DEYU;XU YUANZHI;GONG BENLIANG;DA TINGYU;YAN QUANZHENGJI;CHEN YAOHUAN;ZHOU CHENGMING   

  • Published:1992-07-15

The ENDOR spectra of the15N-63Cu-HAP complex (I) measured in 5:1 DMSO-EtOH solution at 25K were studied by orientation selection technique. The anisotropic superhyperfine coupling tensor of ligand 15N nucleus and the superhyperfine coupling constant of several unequal values of 1H nuclei were determine

Key words: COPPER COMPLEX, ELECTRON SPIN RESONANCE, NITROGEN ISOTOPES, ELECTRON NUCLEAR DOUBLE RESONANCE (ENDOR)

CLC Number: