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Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (7): 722-725. Previous Articles Next Articles
Original Articles
丁渝;沈苗
发布日期:
DING YU;SHEN MIAO
Published:
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(?-Cis-3-(dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid (I) was synthesized through two ways from Et 5-chloro-3,3-dimethylpentanoate (II) which had been obtained from isoprene. The intermediate 4,4-dimethyl-3,4-dihydro-2-pyranone (III) was obtained by phenylthioetherification of II, oxidation to 5-oxo-3,3-dimethylpentanoic acid, and cyclization to III or hydration and acidification of II, esterification and oxidation to Me 5-oxo-3,3-dimethylpentanoate and then cyclization to III.
Key words: SYNTHETIC PYRETHROID-INSECTICIDES, CYCLOPROPANE CARBOXYLIC ACID P, DICHLOROETHYLENE P, CHRYSANTHEMIC
CLC Number:
O621
DING YU;SHEN MIAO. The sysnthesis of (±) cis-3-(dichlorovinyl)-2,2-dimethyl- cyclopropanecarboxylic acid[J]. Acta Chimica Sinica, 1992, 50(7): 722-725.
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