Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (7): 722-725. Previous Articles     Next Articles

Original Articles

合成(±)顺式-3-(二氯乙烯基)-2,2-二甲基环丙烷羧酸的新方法

丁渝;沈苗   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1992-07-15

The sysnthesis of (±) cis-3-(dichlorovinyl)-2,2-dimethyl- cyclopropanecarboxylic acid

DING YU;SHEN MIAO   

  • Published:1992-07-15

(?-Cis-3-(dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid (I) was synthesized through two ways from Et 5-chloro-3,3-dimethylpentanoate (II) which had been obtained from isoprene. The intermediate 4,4-dimethyl-3,4-dihydro-2-pyranone (III) was obtained by phenylthioetherification of II, oxidation to 5-oxo-3,3-dimethylpentanoic acid, and cyclization to III or hydration and acidification of II, esterification and oxidation to Me 5-oxo-3,3-dimethylpentanoate and then cyclization to III.

Key words: SYNTHETIC PYRETHROID-INSECTICIDES, CYCLOPROPANE CARBOXYLIC ACID P, DICHLOROETHYLENE P, CHRYSANTHEMIC

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