Synthesis of Iron and Vanadium Incorporated SBA-15 Molecular Sieves and Its Catalysis for Hydroxylation of Benzene

Acta Chimica Sinica ›› 2007, Vol. 65 ›› Issue (21): 2423-2427. Previous Articles Next Articles

Fe, V取代SBA-15分子筛的合成及其对苯羟基化反应的催化

顾颖颖，李疆，赵新华，王莉萍，单永奎

(华东师范大学化学系上海 200062)

投稿日期:2007-02-27 修回日期:2007-04-26 发布日期:2007-11-14
通讯作者: 单永奎

Synthesis of Iron and Vanadium Incorporated SBA-15 Molecular Sieves and Its Catalysis for Hydroxylation of Benzene

GU Ying-Ying; LI Jiang; ZHAO Xin-Hua; WANG Li-Ping; SHAN Yong-Kui

(Department of Chemistry, East China Normal University, Shanghai 200062)

Received:2007-02-27 Revised:2007-04-26 Published:2007-11-14
Contact: SHAN Yong-Kui

Abstract

Bimetallic iron and vanadium incorporated SBA-15 molecular sieves (FVS) has been hydrothermally synthesized. XRD, TEM and N₂ adsorption-desorption results show that the FVS catalyst has a 2D P6mm hexagonal structure. ESR and UV-vis spectroscopic investigations suggested that the tetrahedrally coordinated iron and vanadium species incorporated within the silica framework. The FVS catalyst exhibited high activity toward hydroxylation of benzene with molecular oxygen, over which the yield of phenol reaches 14.5%.

Key words: SBA-15, mesoporous molecular sieves, bimetallic modification, benzene, hydroxylation

Cite this article

GU Ying-Ying; LI Jiang; ZHAO Xin-Hua; WANG Li-Ping; SHAN Yong-Kui. Synthesis of Iron and Vanadium Incorporated SBA-15 Molecular Sieves and Its Catalysis for Hydroxylation of Benzene[J]. Acta Chimica Sinica, 2007, 65(21): 2423-2427.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Jianqiang Chen, Gangguo Zhu, Jie Wu. Recent Advances in Radical-Based Dehydroxylation of Hydroxyl Groups via Oxalates [J]. Acta Chimica Sinica, 2023, 81(11): 1609-1623.
[2]	Luocong Wang, Zhewei Li, Caiwei Yue, Peihuan Zhang, Ming Lei, Min Pu. Theoretical Study on the Isomerization Mechanism of Azobenzene Derivatives under Electric Field [J]. Acta Chimica Sinica, 2022, 80(6): 781-787.
[3]	Bo Wu, Chong Wang, Baolin Li, Chunru Wang. Light-driven Molecular Magnetic Switch for a Metallofullerene^※ [J]. Acta Chimica Sinica, 2022, 80(2): 101-104.
[4]	Yeming Wang, Hongwei Wang, Zhaohong Liu. Research Progress on EWG-Substituted N-Arylsulfonylhydrazones as the Diazo Compound Precursor [J]. Acta Chimica Sinica, 2021, 79(9): 1085-1096.
[5]	Ni Liao, Xia Zhong, Wen-Bin Liang, Ruo Yuan, Ying Zhuo. Metal-organic Frameworks (MOF)-based Novel Electrochemiluminescence Biosensing Platform for Quantification of H₂O₂ Releasing from Tumor Cells [J]. Acta Chimica Sinica, 2021, 79(10): 1257-1264.
[6]	Liu Xiaojun, Qin Lang, Zhan Yuanyuan, Chen Meng, Yu Yanlei. Phototuning of Structural Colors in Cholesteric Liquid Crystals [J]. Acta Chimica Sinica, 2020, 78(6): 478-489.
[7]	Wang Xiling, Chen Jie, Ma Nana, Cong Zhiqi. Selective Hydroxylation of Alkanes Catalyzed by Cytochrome P450 Enzymes [J]. Acta Chimica Sinica, 2020, 78(6): 490-503.
[8]	Wang Zhiqiang, Bai Meidan, Zhang Ming, Zhang Zhiqiang, Feng Xun, Zheng Caijun. Synthesis and Properties of Two Novel Thermally Activated Delayed Fluorescence Materials with 1,3,5-Tribenzoylbenzene as Electron-Acceptor [J]. Acta Chimica Sinica, 2020, 78(2): 140-146.
[9]	Cheng, Shijie, Zeng, Yang, Pei, Yan, Fan, Kangnian, Qiao, Minghua, Zong, Baoning. Synthesis and Catalysis of Pt/W-s-SBA-15 Catalysts with Short Channel for Glycerol Hydrogenolysis to 1,3-Propanediol [J]. Acta Chimica Sinica, 2019, 77(10): 1054-1062.
[10]	He Yuanyuan, Cheng Na, Zhao Jianwei. Electron Transport Pathways Through One-Dimensional Conjugated Carbon Chain Doped by Thiophene Ring [J]. Acta Chim. Sinica, 2017, 75(9): 893-902.
[11]	Zhou Gongbing, Wang Hao, Pei Yan, Qiao Minghua, Sun Bin, Zong Baoning. Pore Size Effect of Ru-Zn/ZrO₂ Catalyst on Partial Hydrogenation of Benzene to Cyclohexene [J]. Acta Chim. Sinica, 2017, 75(3): 321-328.
[12]	Li Xinwei, Song Song, Jiao Ning. Oxidative Iodohydroxylation of Olefins with DMSO [J]. Acta Chim. Sinica, 2017, 75(12): 1202-1206.
[13]	Dou Rongfei, Tan Xiaohe, Fan Yiqiu, Pei Yan, Qiao Minghua, Fan Kangnian, Sun Bin, Zong Baoning. Study on Ru-B/MIL-53(Al_xCr₁) Catalysts for Partial Hydrogenation ofBenzene to Cyclohexene [J]. Acta Chim. Sinica, 2016, 74(6): 503-512.
[14]	Zhao Qing, Qi Boyu, Wang Baojin, Chen Feiwu. Theoretical Investigation on Weak Interactions of HXeBr with Benzene and Its Derivatives [J]. Acta Chim. Sinica, 2016, 74(3): 285-292.
[15]	Xun Zhiqing, Tang Haiyun, Zeng Yi, Chen Jinping, Yu Tianjun, Zhang Xiaohui, Li Yi. Synthesis and Aggregation-induced Emission of Tetraphenylethylene Derivatives Based on Hexakisphenylbenzene Backbone [J]. Acta Chim. Sinica, 2015, 73(8): 819-825.

Fe, V取代SBA-15分子筛的合成及其对苯羟基化反应的催化

Synthesis of Iron and Vanadium Incorporated SBA-15 Molecular Sieves and Its Catalysis for Hydroxylation of Benzene

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments