Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (3): 269-273. Previous Articles     Next Articles

Original Articles

N,N'-双(2-氨基丙基)草酰胺合铜(II)的铜(II)-锰(II)配合物的合成和磁性

廖代正;林兵;王耕霖   

  1. 南开大学化学系
  • 发布日期:1992-03-15

Synthesis and Magnetism of copper(II)-Manganese(II) complexes with N, N'-Bis(2-aminopropyl)oxamidocopper(II)

LIAO DAIZHENG;LIN BING;WANG GENGLIN   

  • Published:1992-03-15

[Cu(oxap)MnL2](ClO4)2 (I) are synthesized and characterized, (H2oxap = N,N'-bis(2-aminopropyl)oxamide; L 1,10-phenanthroline (phen) or 5-nitro-1,10-phenanthroline (NO2-phen)). Variable-temp. (4.2-300 K) magnetic susceptibility measurements were recorded for I. The exchange integral, J, is -74.72 cm-1 for [Cu(oxap)Mn(phen)2](ClO4)2, and -76.39 cm-1 for [Cu(oxap)Mn(NO2-phen)2](ClO4)2, indicating that a moderately strong antiferromagnetic superexchange interaction operates between the metal ions.

Key words: COPPER COMPLEX, PERCHLORATE, DINUCLEAR COMPLEX, MAGNETISM, MANGANESE COMPLEX, LEAST SQUARE METHODS, MAGNETIZATION, PHENANTHROLINE

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