The structural study of Pd(II), Co(II) complexes of the new(+)-camphor-imind

Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (6): 540-546. Previous Articles Next Articles

Original Articles

新型(十)-樟脑酮亚胺的Pd(II)、Co(II)配合物的晶体结构研究

郭鹏;蒋耀忠;周忠远;胡国志;郁开北

中国科学院成都有机化学研究所;中国科学院成都分析测试中心

发布日期:1990-06-15

The structural study of Pd(II), Co(II) complexes of the new(+)-camphor-imind

GUO PENG;JIANG YAOZHONG;ZHOU ZHONGYUAN;HU GUOZHI;YU KAIBEI

Published:1990-06-15

Abstract

A new chiral ligand I is synthesized from (+)-camphor and 6-methyl-2-(aminomethyl)pyridine, which reacts with Pd(II) and Co(II) to give MLCl2 (M = Pd, Co; L = I). The structure of the complexes is determine by single crystal x-ray diffraction. PdLCl2 is monoclinic, space group P21, Z = 2. CoLCl2 is triclinic, space group P1, Z = 2. The structural characteristics of the complexes are outlined, and IR, UV, NMR are explained.

Key words: ULTRAVIOLET SPECTROPHOTOMETRY, CRYSTAL STRUCTURE DETERMINATION, INFRARED SPECTROPHOTOMETRY, NMR SPECTROMETRY, COBALT COMPLEX, SCHIFF BASE, FOUR-CIRCLE DIFFRACTOMETER, PALLADIUM COMPLEX, CAMPHOR, PYRIDINAMINE P

CLC Number:

O611.662
O74

Cite this article

GUO PENG;JIANG YAOZHONG;ZHOU ZHONGYUAN;HU GUOZHI;YU KAIBEI. The structural study of Pd(II), Co(II) complexes of the new(+)-camphor-imind[J]. Acta Chimica Sinica, 1990, 48(6): 540-546.

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新型(十)-樟脑酮亚胺的Pd(II)、Co(II)配合物的晶体结构研究

The structural study of Pd(II), Co(II) complexes of the new(+)-camphor-imind

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