Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (1): 95-98. Previous Articles     Next Articles

Original Articles

含硫碳负离子的反应及其应用的研究: III, 合成戊烯二酸酯类的新方法

张正;刘广鉴;许从应   

  1. 南京大学化学系
  • 发布日期:1990-01-15

Studies on some reactions of sulfur-containing carbanions and their synthetic applications III: A new method for the synthesis of glutaconates

ZHANG ZHENG;LIU GUANGJIAN;XU CONGYING   

  • Published:1990-01-15

Treatment of the Michael adducts, e.g., PhS(O)CH(CO2Me)CH2CHMeCO2Me with a small amount of CaCO3 in refluxing CCl4 or toluene gave E-glutaconates in 92-94% yields.

Key words: CARBOXYLIC ACID ESTER, INSECT HORMONE, SULFUR COMPOUNDS, PENTENOIC ACID P, JUVENILE HORMONE ANALOGNE, CARBON ION

CLC Number: