Studies on thermochemistry of porphyrins: V. The standard energies of combustion and standard enthalpies of formation of bromoporphyrin compounds

Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (1): 38-41. Previous Articles Next Articles

Original Articles

卟啉化合物的热化学研究: V. 含溴卟啉化合物的标准燃烧能和生成焓

张发明;徐桂端;屈松生

武汉大学化学系

发布日期:1990-01-15

Studies on thermochemistry of porphyrins: V. The standard energies of combustion and standard enthalpies of formation of bromoporphyrin compounds

ZHANG FAMING;XU GUIDUAN;QU SONGSHENG

Published:1990-01-15

Abstract

By using a precision rotating-bomb combustion calorimeter, the standard energies of combustion of squalane, 4-bromobenzoic acid and tetra(p-bromophenyl)porphyrin at 298.15K were determine to be -46.7408 ?0.0117, -15.3774 ?0.0063 and -23.4038 ?0.0121 kJ g-1, resp. The corresponding standard enthalpies of formation at 298.15 K were calculated to be -864.7 ?6.4, -377.4 ?1.6 and 754.2 ?12.6 kJ mol-1.

Key words: PORPHINE P, ORGANO BROMINE COMPOUNDS, DATA HANDLING, COMPUTER APPLICATIONS, BROMOHYDROCARBON, BENZENECARBOXYLIC ACID P, ENTHALPY OF FORMATION, SPINACANE, COMBUSTION PERFORMANCE, THERMOCHEMICAL PROPERTY

CLC Number:

O642

Cite this article

ZHANG FAMING;XU GUIDUAN;QU SONGSHENG. Studies on thermochemistry of porphyrins: V. The standard energies of combustion and standard enthalpies of formation of bromoporphyrin compounds[J]. Acta Chimica Sinica, 1990, 48(1): 38-41.

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卟啉化合物的热化学研究: V. 含溴卟啉化合物的标准燃烧能和生成焓

Studies on thermochemistry of porphyrins: V. The standard energies of combustion and standard enthalpies of formation of bromoporphyrin compounds

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