The low frequency vibrational spectra of some cyclopentyl (phenyl) tertia y phosphine complexes of Ni(II), Pd(II) and Pt(II)

Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (10): 962-966. Previous Articles Next Articles

Original Articles

Ni(II), Pd(II), Pt(II)环戊基(苯基)和膦配合物的低频振动光谱及构型

车迅;宋果男;李同信

中国科学院大连化学物理研究所

发布日期:1989-10-15

The low frequency vibrational spectra of some cyclopentyl (phenyl) tertia y phosphine complexes of Ni(II), Pd(II) and Pt(II)

CHE XUN;SONG GUONAN;LI TONGXIN

Published:1989-10-15

Abstract

The metal complexes with various cyclopentylphenyl tertiary phosphine ligands, MO2L2, (M = Pd, Pt), NiX2L2, (X = Cl, Br, I), L = PPh3-x(C5H9)(x = 0-3), were synthesized. The far-IR and, where possible, low frequency Raman spectra were studied. The M-P and M-X stretching frequencies of some complexes were assigned by analogy with similar assignments and the geometry information were obtained from their spectroscopic feature.

Key words: PHENYL GROUP, INFRARED SPECTROPHOTOMETRY, ORGANO PHOSPHORUS COMPOUNDS, PLATINUM COMPLEX, TRIPHENYLPHOSPHINE, TRANSITION METAL COMPLEX, NICKEL COMPLEX, VIBRATIONAL SPECTRA, PALLADIUM COMPLEX, CONFIGURATION

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CHE XUN;SONG GUONAN;LI TONGXIN. The low frequency vibrational spectra of some cyclopentyl (phenyl) tertia y phosphine complexes of Ni(II), Pd(II) and Pt(II)[J]. Acta Chimica Sinica, 1989, 47(10): 962-966.

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Ni(II), Pd(II), Pt(II)环戊基(苯基)和膦配合物的低频振动光谱及构型

The low frequency vibrational spectra of some cyclopentyl (phenyl) tertia y phosphine complexes of Ni(II), Pd(II) and Pt(II)

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