Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (11): 1105-1108. Previous Articles     Next Articles

Original Articles

全氟烷基亚磺酸盐的反应II. 一种合成N,N-双金氟烷基羟胺的新法

黄维垣;胡里清;葛文正   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1988-11-15

The reactions of perfluoroalkanesulfinates II: A new method for the synthesis of N,N-bisperfluoroalkylhydroxylamine

HUANG WEIYUAN;HU LIQING;GE WENZHENG   

  • Published:1988-11-15

Reaction of sodium perfluoroalkanesulfinates RCF2SO2Na [R = Cl(CF2)3, Cl(CF2)5, Cl(CF2)8OCF2] with nitric acid, nitrous acid or nitrogen dioxide in aqueous solution gave a moderate yield of N,N-bisperfluoroalkylhydroxylamines accompanied by perfluorocarboxylic acids and their amides as well as nitroso perfluoroalkanes.

Key words: NITRIC ACID, NITROGEN OXIDE, SULFONATE, HYDROXYLAMINES, PERFLUORO-HYDROCARBON, PERFLUORO-HYDROCARBON

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