Studies on olefin-coordinating transition metal carbene complexes VI: Synthesis and crystal structure of two novel inner salt complexes of iron

Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (9): 875-880. Previous Articles Next Articles

Original Articles

含烯烃配体的过渡金属卡宾配合物的研究VI: 两个新奇的铁内盐配合物的合成和晶体结构

殷建国;陈家碧;徐维铧;徐筱杰;唐有祺

中国科学院上海有机化学研究所;北京大学物理化学研究所

发布日期:1988-09-15

Studies on olefin-coordinating transition metal carbene complexes VI: Synthesis and crystal structure of two novel inner salt complexes of iron

YIN JIANGUO;CHEN JIABI;XU WEIHUA;XU XIAOJIE;TANG YOUQI

Published:1988-09-15

Abstract

(Cinnamylidenexylidine)(tricarbonyl)iron reacted with phenyllithium and p-chlorophenyllithium at low temperature; the adducts formed were alkylated with Et3O+.BF4- in CH2Cl2 at -60?to give two novel zwitterionic iron complexes I (R = Ph, 4-ClC6H4). The crystal structure of I (R = Ph) was determine

Key words: CRYSTAL STRUCTURE DETERMINATION, BENZAMINE P, DIMETHYL GROUP, IRON COMPLEX, CARBONYL COMPLEX, ALKYLATION, CARBENE, STERIC EFFECT, TRANSITION METAL COMPLEX, MATRICES

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YIN JIANGUO;CHEN JIABI;XU WEIHUA;XU XIAOJIE;TANG YOUQI. Studies on olefin-coordinating transition metal carbene complexes VI: Synthesis and crystal structure of two novel inner salt complexes of iron[J]. Acta Chimica Sinica, 1988, 46(9): 875-880.

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含烯烃配体的过渡金属卡宾配合物的研究VI: 两个新奇的铁内盐配合物的合成和晶体结构

Studies on olefin-coordinating transition metal carbene complexes VI: Synthesis and crystal structure of two novel inner salt complexes of iron

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