Mossbauer analysis of Bis(π-arene) iron(II) compounds

Abstract

The Moessbauer parameters of eight bis(p-arene)iron(II) compounds are reported, and the relationship of the parameters with the structure of these compounds has been analyzed. The results indicate that bis(p-arene)iron(II) compounds are covalently paramagnetic, and there may exist electron-transfer from the B12H122- anion to the bis(p-arene)iron(II) cation in [R2Fe]B12H12 (R = substituted benzene, tetrahydronaphthalene).

Key words: IRON COMPLEX, ORGANOMETALLIC COMPOUNDS, AROMATIC COMPOUNDS, CONFIGURATION, SANDWICH COMPOUNDS, MOSSBAUER SPECTROMETRY

CLC Number:

O657
O627

Cite this article

FANG XINQIN;ZHANG LUN;YAN XIAOHUA;CHEN YILONG. Mossbauer analysis of Bis(π-arene) iron(II) compounds[J]. Acta Chimica Sinica, 1988, 46(1): 66-68.

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双(π-芳烃)铁(II)化合物的Mossbauer分析