Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (4): 408-411. Previous Articles     Next Articles

Original Articles

PMP的酰化反应及其产物萃取性能的研究

赵逸云;刘复初;赵雁来   

  1. 云南大学化学系
  • 发布日期:1987-04-15

The study of acylation of 1-phenyl-3-methyl-5-pyrazolone (PMP) and extractability of the products

ZHAO YIYUN;LIU FUCHU;ZHAO YANLAI   

  • Published:1987-04-15

Nine new alkoxybenzoyl derivatives of 1-phenyl-3-methyl-5-pyrazolone (PMP), including 5 C-acyl, 2 O-acyl and 2 C,O-diacyl derivatives, were synthesized. The study of acylation of PMP under different condition showed that the amts. of acyl chlorides and nature and amts. of bases used have great influence on the direction of the reaction. Preliminary extration studies of La and Y by the 5 C-alkoxylbenzoyl-PMPs showed that the extration power of 4-(3,4,5-trimethoxybenzoyl)-3-methyl-1-phenyl-5-pyrazolone is better than that of PMBP.

Key words: AQUEOUS SOLUTION, EXTRACTION, CHLOROFORM, PYRAZOLONE P, LANTHANUM, YTTRIUM, N-PHENYL GROUP, ACYLATION, BETA DIKETONES

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