Mixed Proton Electrolyte of Acetic Acid Containing Boron Trifluoride Diethyl Etherate

Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (18): 1929-1932. Previous Articles Next Articles

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乙酸-三氟化硼乙醚混合质子电解质

马茶¹, 徐景坤*^,1, 周卫强¹, 杜玉扣²

(¹江西科技师范学院江西省有机功能分子重点实验室南昌 330013)
(²苏州大学化学化工学院物理化学研究室苏州 215006)

投稿日期:2005-10-24 修回日期:2005-12-21 发布日期:2006-09-28
通讯作者: 徐景坤

Mixed Proton Electrolyte of Acetic Acid Containing Boron Trifluoride Diethyl Etherate

MA Cha¹; XU Jing-Kun*^,1; ZHOU Wei-Qiang¹; DU Yu-Kou²

(¹ Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science & Technology Normal Univer-sity, Nanchang 330013)
(²Department of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006)

Received:2005-10-24 Revised:2005-12-21 Published:2006-09-28
Contact: XU Jing-Kun

Abstract

Although the ionic conductivities of pure acetic acid and pure boron trifluoride diethyl etherate (BFEE) are very low, acetic acid containing certain amount of boron trifluoride diethyl etherate can form good mixed proton electrolyte with ionic conductivity maximum of 5.8×10³ μS/cm when BFEE molar fraction is 65%. The IR and ¹H NMR spectra of the mixed electrolyte indicate that the main conductive species in mixed electrolytes are CH₃COOH₂^＋ and CH₃COOBF₃^－.

Key words: mixed proton electrolyte, acetic acid, boron trifluoride diethyl etherate, ¹H NMR

Cite this article

MA Cha; XU Jing-Kun*^,1; ZHOU Wei-Qiang; DU Yu-Kou². Mixed Proton Electrolyte of Acetic Acid Containing Boron Trifluoride Diethyl Etherate[J]. Acta Chimica Sinica, 2006, 64(18): 1929-1932.

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乙酸-三氟化硼乙醚混合质子电解质

Mixed Proton Electrolyte of Acetic Acid Containing Boron Trifluoride Diethyl Etherate

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