Syntheses and Anion Recognition of Novel Calix[4]resorcinarene Thiourea Derivatives

Acta Chimica Sinica ›› 2005, Vol. 63 ›› Issue (6): 533-537. Previous Articles Next Articles

Original Articles

新型间苯二酚杯芳烃硫脲衍生物对阴离子的识别

戈云，刘莉，王云艳，颜朝国*

(扬州大学化学化工学院　扬州 225002)

投稿日期:2004-04-28 修回日期:2004-11-24 发布日期:2010-12-10
通讯作者: 颜朝国

Syntheses and Anion Recognition of Novel Calix[4]resorcinarene Thiourea Derivatives

GE Yun, LIU Li, WANG Yun-Yan, YAN Chao-Guo*

(College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002)

Received:2004-04-28 Revised:2004-11-24 Published:2010-12-10
Contact: YAN Chao-Guo

Abstract

Four novel calix[4]resorcinarene-based amide derivatives containing eight or twelve terminal phenylthiourea groups were smoothly synthesized in three steps from the corresponding calix[4]- resorcinarenes in good yields. Their structures were characterized by elemental analysis and ¹H NMR, IR, UV spectra. The binding properties of the two representative THBC and TPBC for anions with UV-vis spectra were studied. They showed better recognition ability for AcO^－, H₂PO₄^－ and HSO₄^－ anions to form 1∶3 stoichiometric complexes.

Key words: calix[4]resorcinarene, thiourea, anion recognition, UV-vis spectra, supramolecular chemistry

Cite this article

GE Yun, LIU Li, WANG Yun-Yan, YAN Chao-Guo*. Syntheses and Anion Recognition of Novel Calix[4]resorcinarene Thiourea Derivatives[J]. Acta Chimica Sinica, 2005, 63(6): 533-537.

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新型间苯二酚杯芳烃硫脲衍生物对阴离子的识别

Syntheses and Anion Recognition of Novel Calix[4]resorcinarene Thiourea Derivatives

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