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Acta Chimica Sinica ›› 1998, Vol. 56 ›› Issue (7): 644-648. Previous Articles Next Articles
Original Articles
安学勤;蒋富国;陈传缨;周从山;方建;沈伟国
发布日期:
AN XUEQIN;JIANG FUGUO;CHEN CHUANYING;ZHOU CONGSHAN;FANG JIAN;SHEN WEIGUO
Published:
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A series of turbidity measurements have been made for nitrobenzene in hexadecane in the critical region at various wavelengths and temperatures. Critical amplitudes ξ0, x0 and B corresponding to the correlation length, the susceptibility and the coexistence curve are related through R=ξ0[B^2/(4kBTcx0)]^1^/^3, where the value of R is 0.65-0.67. By using this relation the turbidity data have been fitted to Ornstein-Zernike equation to obtain critical exponents γ and ν, which are consistent with the theoretical values within experimental uncertainties. The experimental data have also been analyzed to determine critical amplitudes when the value of γ and ν are fixed at their theoretical values 1.241 and 0.63. The results have shown that ξ0 is 0.168nm (R=0.65) and 0.174nm (R=0.67), and x0 is 2.81×10^-^9m^3.J^-^1(R=0.65) and 2.85×10^-^9m^3.J^-^1 (R=0.67), respectively.
Key words: NITROBENZENE, TURBIDITY, LIGHT SCATTERING, CRITICAL REGION, DIOCTYL
CLC Number:
O645
AN XUEQIN;JIANG FUGUO;CHEN CHUANYING;ZHOU CONGSHAN;FANG JIAN;SHEN WEIGUO. Turbidity measurements of nitrobenzene in hexadecane in the critical region[J]. Acta Chimica Sinica, 1998, 56(7): 644-648.
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MA, Lin *,a LIU, Dong-Qun a LIU, Chun-Li b XU, Li c LIN, Rui-Sen c TONG, Zhang-Fa a