Influence of Surfactant on Electrochemical Behavior of Gold Electrode Modified with Thiol Monolayer

Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (13): 1309-1313. Previous Articles Next Articles

Original Articles

表面活性剂对硫醇单层膜修饰金电极电化学行为的影响

马勇¹,2，王建国²，惠飞²，霍俊杰²，臧树良*^,1,2

(¹华东师范大学化学系上海 200062)
(²辽宁大学稀散金属研究所沈阳 110036)

投稿日期:2005-08-02 修回日期:2006-03-14 发布日期:2006-07-14
通讯作者: 臧树良

Influence of Surfactant on Electrochemical Behavior of Gold Electrode Modified with Thiol Monolayer

MA Yong¹,2, WANG Jian-Guo², HUI Fei², HUO Jun-Jie², ZANG Shu-Liang*^,1,2

(¹Department of Chemistry, East China Normal University, Shanghai 200062)
(²Institute of Rare and Scattered Metal Chemistry, Liaoning University, Shenyang 110036)

Received:2005-08-02 Revised:2006-03-14 Published:2006-07-14
Contact: ZANG Shu-Liang

Abstract

Self-assembled monolayer of 1-dodecanethiol was prepared on gold electrode. The different kinds of probes such as ferrocyanide/ferricyanide, dopamine, ascorbic acid and hydroquinone were used to investigate the electron-transfer process in the presence of surfactant hexadecyltrimethylammonium bromide. Cyclic voltammetry and electrochemical impedance spectroscopy studies showed the selective electrochemical recognition of probe molecules in solution on self-assembled monolayer of thiol, and the possible mechanism was also discussed.

Key words: self-assembled monolayer, surfactant, cyclic voltammetry, ac impedance

Cite this article

MA Yong^1,2, WANG Jian-Guo², HUI Fei², HUO Jun-Jie², ZANG Shu-Liang*^,1,2. Influence of Surfactant on Electrochemical Behavior of Gold Electrode Modified with Thiol Monolayer[J]. Acta Chimica Sinica, 2006, 64(13): 1309-1313.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Chenyu Liao, Shanwei Guo, Meiwei Huang, Yong Guo, Qing-Yun Chen, Chao Liu, Yunwen Zhang. Synthesis and Properties of Fluoroether Phosphocholine [J]. Acta Chimica Sinica, 2024, 82(1): 46-52.
[2]	Rong Zhang, Jiangping Liu, Ziyi Zhu, Shumei Chen, Fei Wang, Jian Zhang. Synthesis, Structure and Characterization of Two Ferrocene Functionalized Cadmium Metal Organic Frameworks^※ [J]. Acta Chimica Sinica, 2022, 80(3): 249-254.
[3]	Lin Li, Zizhao Wang, Jiawei Liu, Jia Chen, Xiao Jin, Caili Dai. Synthesis and Performance Evaluation of Polyhydroxy Benzene Sulfonate Oil Displacement Agent Based on Enhanced Interfacial Wettability Control [J]. Acta Chimica Sinica, 2022, 80(1): 63-68.
[4]	Zhu Congtan, Yang Ying, Zhao Beikai, Lin Feiyu, Luo Yuan, Ma Shupeng, Zhu Liu, Guo Xueyi. Electrochemical Synthesis of PEDOT and Its Application in Solid-State Dye-sensitized Solar Cells [J]. Acta Chimica Sinica, 2020, 78(10): 1102-1110.
[5]	Wang Zhitao, Li Hui, Yan Shichen, Fang Qianrong. Synthesis of a Two-dimensional Covalent Organic Framework with the Ability of Conducting Proton along Skeleton [J]. Acta Chimica Sinica, 2020, 78(1): 63-68.
[6]	Song Guangjie, Wu Tiaodi, Liu Fuxin, Zhang Binyan, Liu Xiuhui. Electrochemical Detection of Xanthine and Study for the Inhibition of Uric Acid Based on Chitosan/Nitrogen Doped Reduced Graphene Oxide Modified Electrode [J]. Acta Chimica Sinica, 2020, 78(1): 82-88.
[7]	Zhao Weiwei, Wang Yilin. Development of Surfactant Application in Wastewater Treatment [J]. Acta Chim. Sinica, 2019, 77(8): 717-728.
[8]	Chen Tian, Yang Ying, Zhao Wanyu, Pan Dequn, Zhu Congtan, Lin Feiyu, Guo Xueyi. Solvothermal Preparation and Characterization of Nano-nickel Oxide [J]. Acta Chim. Sinica, 2019, 77(5): 447-454.
[9]	Wang, Ziyan, Khalid, Hira, Li, Baili, Li, Yao, Yu, Xi, Hu, Wenping. Tuning Rectification Properties of Molecular Electronic Devices by Mixed Monolayer [J]. Acta Chimica Sinica, 2019, 77(10): 1031-1035.
[10]	Li Haofei, Qiao Fulin, Fan Yaxun, Wang Yilin. Aggregation in the Mixture of Branched Carboxylate Salts and Sulfonate Surfactants with Different Oligomeric Degrees [J]. Acta Chim. Sinica, 2018, 76(7): 564-574.
[11]	Yan Nana, Xiao Tianliang, Liu Zhaoyue. Monolayer-gated Ion Transport in Artificial Ion Channels Based on A Nanoporous Gold Membrane [J]. Acta Chim. Sinica, 2017, 75(9): 873-877.
[12]	Ma Hui, Ma Wei, Yang Zheyao, Ding Zhifeng, Long Yi-Tao. Characterization of Steady-State Current at Nanoelectrodes [J]. Acta Chim. Sinica, 2017, 75(11): 1082-1086.
[13]	Zhang Na, Chen Guojun, Chen Kun, Li Hongguang, Hao Jingcheng. Viscoelastic Emulsions Stabilized by Salt-Free Catanionic Surfactants [J]. Acta Chim. Sinica, 2015, 73(8): 835-839.
[14]	Sha Min, Zhang Ding, Pan Renming, Xing Ping, Jiang Biao. Synthesis and Properties Study of Novel Branched Fluorinated Surfactants with CF₃CF₂CF₂C(CF₃)₂ Group [J]. Acta Chim. Sinica, 2015, 73(5): 395-402.
[15]	Tang Yongqiang, Zhu Linyi, Han Yuchun, Wang Yilin. Effects of Branched-Chain Alcohols on Surface Activity and Micellization of Gemini Surfactants [J]. Acta Chimica Sinica, 2014, 72(6): 673-681.

表面活性剂对硫醇单层膜修饰金电极电化学行为的影响

Influence of Surfactant on Electrochemical Behavior of Gold Electrode Modified with Thiol Monolayer

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments