Acta Chimica Sinica ›› 2000, Vol. 58 ›› Issue (7): 871-875. Previous Articles     Next Articles

Original Articles

平面手性二茂铁亚胺环钯、环汞化合物与金属锡的 金属转移反应

吴养洁;崔秀灵;侯建军;杨亮茹;王敏;杜晨霞;朱玉   

  1. 郑州大学化学系.郑州(450052);河南省高校应用化学重点实验室
  • 发布日期:2000-07-15

Transmetallation reactions of planar chiral cyclopalladated and cyclomercurated ferrocenylimines with metallic tin

Wu Yangjie;Cui Xiuling;Hou Jianjun;Yang Liangru;Wang Min;Du Chenxia;Zhu Yu   

  1. Zhengzhou Univ, Dept Chem.Zhengzhou(450052)
  • Published:2000-07-15

A series of optically active cyclostannated ferrocenylimines were synthesized by transmetallation of optically active cyclopalladated and cyclomercurated ferrocenylimines with metallic tin, respectively. All of the yielded compounds were characterized by elemental analysis, IR and ^1H NMR. The crystal structures and absolute configurations of the complex were determined by X-ray diffraction and checked by CD spectra.

Key words: FERROCENE P, PALLADIUM COMPOUNDS, MERCURY COMPOUNDS, TIN, X-RAY DIFFRACTION ANALYSIS, CRYSTAL STRUCTURE

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