Acta Chimica Sinica ›› 2001, Vol. 59 ›› Issue (9): 1372-1375. Previous Articles     Next Articles

Original Articles

SrB4O7:Pr^3+中Pr^3+的发光性质

杨智;林建华;苏勉曾;陶冶;王谓;李国宝;王宇飞;李永明   

  1. 云南师范大学化学系;北京大学稀土材料化学与应用国家重点实验室;中国科学 院高能物理研究所同步辐射实验室
  • 发布日期:2001-09-15

Luminescent property of Pr^3+ in BrB4O7

Yang Zhi;Lin Jianhua;Su Mianzeng;Tao Ye;Wang Wei;Li Guobao;Wang Yufei;Li Yongming   

  • Published:2001-09-15

The luminescent property of Pr^3+ in SrB4O7 is reported. The energy level of Pr^3+ 4f5d in SrB4O7 lies above the 1^S0 state. so under UV light excitation at 207 nm, cascade emission of Pr^3+ occurs from the 1^S0 state in SrB4O7:Pr^3+(x=0.0050) or which converts a single UV photon of high energy into two visible photons. The cascade emission observed with this oxide matrix is largely due to the weak crystal field on the cation sites. Analysis of the vibrational coupling indicates that the radiative transition from the 3^P0 state is related to the low photon frequency of the borate groups (BO4) bonded to the Sr^2+ (or Pr^3+) ions (hωmax=~1200 cm^-1). The 1^So→ 1^G4(313nm), 1^S0→1^D2(338nm) and 1^S0→1^I6(405nm) transitions are responsible for the first photon emission. The second photon emission originates from the transitions from the intermediate energy levels (3^P0 and 1^D2) to the lower energy levels [3^P0→(3^HJ, 3^FJ) and 1^D2→(3^H4, 3^H5).

Key words: STRONTIUM OXIDE, BORON OXIDE, PRASEODYMIUM, CHARACTERISTICS OF LUMINESCENCE

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