Preparation of New Aqueous Cobalt Phthalocyanines and Their Catalytic Oxidation of Thiol

Acta Chimica Sinica ›› 2005, Vol. 63 ›› Issue (6): 507-511. Previous Articles Next Articles

Original Articles

新型水溶性钴酞菁的制备及其催化氧化硫醇的性能

陈文兴*^,1，吕素芳¹，潘勇²，胡智文¹

(¹浙江理工大学先进纺织材料与制备技术教育部重点实验室　杭州 310018)
(²浙江大学材料化学学院高分子系　杭州 310027)

投稿日期:2004-08-06 修回日期:2004-11-20 发布日期:2010-12-10
通讯作者: 陈文兴

Preparation of New Aqueous Cobalt Phthalocyanines and Their Catalytic Oxidation of Thiol

CHEN Wen-Xing*^,1, LÜ Su-Fang¹, PAN Yong², HU Zhi-Wen¹

(¹Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Zhejiang Sci-Tech University, Hangzhou 310018)
(²Department of Polymer Science and Technology, Zhejiang University, Hangzhou 310027)

Received:2004-08-06 Revised:2004-11-20 Published:2010-12-10
Contact: CHEN Wen-Xing

Abstract

Cobalt tetraaminophthalocyanine was modified by butanedioic anhydride and maleic anhydride to get two aqueous cobalt phthalocyanines. The catalytic oxidation activity of these two cobalt phthalocyanines toward 2-mercaptoethanol was measured, and the effects of pH, temperature and time on the catalytic oxidation activity were investigated. The results reveal the best catalytic oxidation activity at pH 11. The catalytic oxidation activity was improved with the rising of temperature.

Key words: cobalt phthalocyanine, butanedioic anhydride, maleic anhydride, catalytic oxidation

Cite this article

CHEN Wen-Xing*^,1, LÜ Su-Fang, PAN Yong², HU Zhi-Wen. Preparation of New Aqueous Cobalt Phthalocyanines and Their Catalytic Oxidation of Thiol[J]. Acta Chimica Sinica, 2005, 63(6): 507-511.

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新型水溶性钴酞菁的制备及其催化氧化硫醇的性能

Preparation of New Aqueous Cobalt Phthalocyanines and Their Catalytic Oxidation of Thiol

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