Acta Chimica Sinica ›› 1999, Vol. 57 ›› Issue (5): 437-445.     Next Articles

Original Articles

反胶束系统及萃取蛋白质的分子热力学模型1: 反胶束系统的分 子热力学模型

周世琦;郭祀远   

  1. 华东理工大学化学系.上海(200237);华南理工大学轻化工研究所
  • 发布日期:1999-05-15

Molecular thermodynamic model for reverse micelles system and protein extraction 1: Molecular thermodynamic model for reverse micelles system

Zhou Shiqi;Guo Siyuan   

  1. East China Univ of Sci Tech., Dept Chem.Shanghai(200237)
  • Published:1999-05-15

A thermodynamic molecular model is presented by analyzing three effects related to the formation of reverse micelles system comprehensively i.e. low interfacial tension effect, interfacial bending effect, mixing entropy effect, based on thermodynamic analysis on the stability of reverse micelles system. The predicted changes in water content of reverse micelles system with the variation of inorganic salt type and concentration, surfactant concentration and consurfactant content are in accordance with the experimental law obtained quantitatively. The model can also predict electrostatic potential value on the inside surface of the reverse micelles system and surfactant dissociation degree.

Key words: EXTRACTION, PROTEIN, SURFACTANTS

CLC Number: