Study on phase chemistry of coordination of zinc salts  to L-α- Histidine

Acta Chimica Sinica ›› 1999, Vol. 57 ›› Issue (5): 485-490. Previous Articles Next Articles

Original Articles

锌盐与L-α-组氨酸配合行为的相化学研究

刘建睿;侯育冬;高胜利;冀棉;史启祯

西北大学化学系.西安(710069)

发布日期:1999-05-15

Study on phase chemistry of coordination of zinc salts to L-α- Histidine

Liu Jianrui;Hou Yudong;Gao Shengli;Ji Mian;Shi Qizhen

Northwest Univ, Dept Chem.Xian(710069)

Published:1999-05-15

Abstract

The solubility properties of the ZnCl~2/Zn(OAc)~2/ZnSO~4-His-H~2O systems at 25℃ in the whole concentration ranges have been investigated by semimicro phase equilibrium method, and the corresponding equilibrium diagram and refractive index diagram were constructed. The incongruently soluble compound of Zn(His)Cl~2. 1/2H~2O and congruently soluble compounds of Zn(His)(OAc)~2.1/2H~2O and Zn(His)SO~4.H~2O, which are not reported in literatures are discovered and synthesized. These compounds are charactered by IR spectra, TG-DTG, X-ray diffraction, as well as chemical and elemental analyses.

Key words: ZINC CHLORIDE, ZINC SULFATE, ZINC ACETATE, HISTIDINE, PHASE EQUILIBRIUM, TERNARY SYSTEM, ELEMENTAL ANALYSIS, INFRARED SPECTROPHOTOMETRY, THERMOGRAVIMETRY, ZINC COMPLEX

CLC Number:

O642

Cite this article

Liu Jianrui;Hou Yudong;Gao Shengli;Ji Mian;Shi Qizhen. Study on phase chemistry of coordination of zinc salts to L-α- Histidine[J]. Acta Chimica Sinica, 1999, 57(5): 485-490.

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锌盐与L-α-组氨酸配合行为的相化学研究

Study on phase chemistry of coordination of zinc salts to L-α- Histidine

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