Electrosynthesis and Characterization of Free-standing Polyacrylate Functionalized Polycarbazole Network Films

Acta Chimica Sinica ›› 2010, Vol. 68 ›› Issue (06): 564-570. Previous Articles Next Articles

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聚丙烯酸修饰咔唑的电化学聚合及表征

朱召进¹^{,2，徐景坤*^{,1，裴梅山*^{,2，卢宝阳¹，马茶^1，李龙¹，申亮¹}}}

(¹江西科技师范学院江西省有机功能分子重点实验室南昌 330013)
(²济南大学化学化工学院济南 250022)

投稿日期:2009-07-24 修回日期:2009-10-04 发布日期:2010-03-28
通讯作者: 徐景坤 E-mail:xujingkun@mail.ipc.ac.cn;xujingkun@tsinghua.org.cn

Electrosynthesis and Characterization of Free-standing Polyacrylate Functionalized Polycarbazole Network Films

Zhu Zhaojin¹^{,2 Xu Jingkun*^{,1 Pei Meishan*^{,2 Lu Baoyang¹ Ma Cha¹ Li Long¹ Shen Liang¹}}}

(¹ Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013)
(²College of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022)

Received:2009-07-24 Revised:2009-10-04 Published:2010-03-28

Abstract

A novel acrylate functionalized with pendant carbazole monomer, N-[6-(acryloxy)hexyl]-carbazole (MACZ), was synthesized. The radical polymerization of MACZ led to the formation of a precursor polymer, poly(N-[6-(acryloxy)hexyl]carbazole) (PMACZ). Free-standing and conducting conjugated polycarbazole network poly-{poly(N-[6-(acryloxy)hexyl]carbazole)} (PPMACZ) films were synthesized electrochemically by direct anodic oxidation of PMACZ, which showed good electrochemical behavior and good thermal stability with conductivity of 1.34×10^－5 S•cm^－1, and were characterized by UV-Vis, infrared, fluorescence spectroscopy and thermal analysis. Fluorescence spectral studies revealed that the PPMACZ films were good blue light emitters.

Key words: polycarbazole, conducting polymer, polyacrylate, electrochemical polymerization, network film

Cite this article

SHU Shao-Jin, XU Jing-Kun, FEI Mei-Shan, LEI Bao-Yang, MA Cha, LI Long, SHEN Liang. Electrosynthesis and Characterization of Free-standing Polyacrylate Functionalized Polycarbazole Network Films[J]. Acta Chimica Sinica, 2010, 68(06): 564-570.

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聚丙烯酸修饰咔唑的电化学聚合及表征

Electrosynthesis and Characterization of Free-standing Polyacrylate Functionalized Polycarbazole Network Films

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