Acta Chimica Sinica ›› 2010, Vol. 68 ›› Issue (07): 623-632. Previous Articles     Next Articles

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(H2+CO+CH4+Air)多元爆炸性混合气体爆炸形态与波形的区划

胡锐1,吴小华2,胡耀元*,1   

  1. (1浙江师范大学基建处 金华 321004)
    (2浙江师范大学化学系 金华 321004)
  • 投稿日期:2009-05-21 修回日期:2009-09-27 发布日期:2010-04-14
  • 通讯作者: 胡耀元 E-mail:chuyy@mail.zjnu.cn
  • 基金资助:

    浙江省自然科学基金资助项目(295001)

Compartmentalization of Explosive Morphology and Waveforms of Multicomponent Gas Mixture Consisting of H2, CO, CH4 and Air

Hu Rui1 Wu Xiaohua2 Hu Yaoyuan*,1   

  1. (1 Capital Construction Office of Zhejiang Normal University, Jinghua 321004)
    (2 Department of Chemistry, Zhejiang Normal University, Jinghua 321004)
  • Received:2009-05-21 Revised:2009-09-27 Published:2010-04-14

Systematic studies were carried out to investigate the explosion characteristics and morphology of the multicomponent explosive gas mixture (H2, CO, CH4 and Air). The explosive limits of concentration, explosive morphology, explosive pressure waveforms and their influence factors were investigated. The explosive danger degree, the flame spreading limit, the minimum ignition energy and other explosive characteristics of the multicomponent explosive gas mixture were determined by experiments. Based on the various explosive morphologies and their pressure waveforms obtained, a new scientific compartmentalization of explosive morphology for the multicomponent explosive gas mixture was proposed for the first time. Within the explosive limits, the explosive morphology can be further compartmentalized into four kinds of explosive morphologies (cold flame, deflagration, detonation and deflagration to detonation transition) and six explosive zones (the upper and lower cold flame zones, the upper and lower deflagration zones, the detonation zone and the lower deflagration to detonation transition zone). The different mechanisms for developing the pressure waves of the explosive morphology were explored. Such knowledge is valuable for further studying the relevant system of branched-chain explosion and developing the theory of branched-chain explosion. The explosive danger degree, the flame spreading limit, the minimum ignition energy and other explosive characteristics of the multicomponent explosive gas mixture were obtained, which are helpful for instituting the explosion-proof safety guidelines for the multicomponent explosive gas mixture discussed. This study also introduced the concept of “key components” and points out that it is the key components of H2 and oxidant O2 that ignite explosion. The references and methods for developing the explosion-proof safety guidelines were proposed. The results will be of significance in preventing accidents caused by mixture gas branched-chain explosion, giving directions to designing of explosion-proof electric equipment and fire arresters, supervising the application of the concepts of branched-chain burning and branched-chain explosion to practice.

Key words: branched chain explosion, explosive limit of concentration, explosive morphology, explosive waveform, key component, the explosion-proof safety guideline