Acta Chimica Sinica ›› 2010, Vol. 68 ›› Issue (12): 1229-1234. Previous Articles     Next Articles

Special Topic

高温高矿化度条件下驱油剂中聚合物分子结构形态及其在中低渗油层中的渗流特性

卢祥国*,王晓燕*,李强,王荣健   

  1. 大庆石油学院 提高油气采收率教育部重点实验室 黑龙江 大庆 163318
  • 投稿日期:2009-05-30 修回日期:2010-01-14 发布日期:2010-02-10
  • 通讯作者: Wang Xiaoyan E-mail:wxyanlove@163.com
  • 基金资助:

    国家科技重大专项“海上油田丛式井网整体加密及综合调整技术”经费资助(编号:2008ZX05024-04)

The Polymer Molecular Configuration in the Oil Displacement Agent with High Temperature and Salinity and Its Seepage Property in the Medium-Low Permeability Layer

LU Xiang-Guo, WANG Xiao-Yan, LI Qiang, WANG Rong-Jian   

  1. Key Laboratory of Enhanced Oil Recovery, Ministry of Education, Daqing Petroleum Institute, Daqing 163318
  • Received:2009-05-30 Revised:2010-01-14 Published:2010-02-10
  • Contact: 王晓燕 Xiaoyan E-mail:wxyanlove@163.com

The dimension of polymer molecular coil in polymer solution and "polymer/surfactant" displacement system and its influential factors were studied under the condition of high temperature and salinity, as well as the seepage property under the medium-low permeability reservoir environment, and the mechanism of their flowing rule was also analyzed, by making use of dynamic light scattering (DLS), scanning electron microscopy (SEM) and core flow experiment. The results show that, under the condition of high temperature and salinity, the dimensions of polymer molecular coils (Dh) both in the polymer solution and "polymer/surfactant" displacement system present a variation rule of "increases first and then decreases", with the polymer concentration increases. In addition, the surfactant is absorbed to polymer molecule in the form of micellar aggregate, resulting in a greater Dh in the "polymer/surfactant" displacement system when compared to the polymer solution. Under the condition of high salinity of solvent water and medium-low core permeability, the erosion and dilution of following injecting water can result in a concentration decreasing of retained polymer in the core, thereby the Dh increases, and eventually the residual resistance factors both of the polymer solution and "polymer/surfactant" system are greater than their resistance factors.

Key words: polymer solution, polymer/surfactant displacement system, salinity, configuration, molecular coil dimension, seepage property, mechanism analysis