Acta Chimica Sinica ›› 2010, Vol. 68 ›› Issue (21): 2231-2237. Previous Articles     Next Articles

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有机/无机复合介孔膜的合成及其生物酶吸附行为研究

朱瑾瑜,沈逸,吴龙,甘思文,陈安琪,沈祝萍,潘小庆,陈勇*   

  1. (上海应用技术学院化学与环境工程学院 上海 200235)
  • 投稿日期:2009-11-13 修回日期:2010-05-13 发布日期:2010-07-08
  • 通讯作者: 陈勇 E-mail:yongchen@sit.edu.cn
  • 基金资助:

    国家自然科学基金;教育部归国留学人员基金;上海市教委科技创新基金;上海市教委资助项目

Studies on the Synthesis of Organic/Inorganic Hybrid Mesoporous Silica Membrane and Its Adsorption Behavior of Enzyme

ZHU Jin-Yu, SHEN Yi, WU Long, GAN Si-Wen, CHEN An-Qi, SHEN Zhu-Ping, PAN Xiao-Qing, CHEN Yong   

  1. (School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 200235)
  • Received:2009-11-13 Revised:2010-05-13 Published:2010-07-08
  • Contact: CHEN Yong E-mail:yongchen@sit.edu.cn

An organic/inorganic hybrid membrane composed of one-dimensional mesoporous silica rodlike materials inside the channels of polycarbonate filtration membrane (PC) was synthesized by using PC as the hard template and characterized by SEM, EDS and TEM. The experimental results demonstrate that the length and diameter of the one-dimensional silica rods formed inside the channels of PC are 9 μm and 200 nm, respectively. Moreover, it is found that as-synthesized silica rods in PC are mixed with the disordered warmlike and the ordered cubic mesophase structure, and the diameter of mesopores with cubic mesophase is estimated to be 8.5 nm. In addition, the adsorption behavior of myoglobin into such a membrane was investigated, and the adsorption amount was evaluated to be 5.85 mg/g.

Key words: mesoporous material, hybrid membrane, template synthesis, polycarbonate membrane, myoglobin

CLC Number: