Acta Chimica Sinica ›› 2011, Vol. 69 ›› Issue (01): 1-7.     Next Articles

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共价键联的多金属氧酸盐/SBA-15介孔杂化材料的电化学性质研究

罗秀娟,杨春*,陈煜   

  1. (江苏省生物功能材料重点实验室 南京师范大学化学与材料科学学院 南京 210097)
  • 投稿日期:2010-07-13 修回日期:2010-09-01 发布日期:2010-09-07
  • 通讯作者: 杨春 E-mail:yangchun@njnu.edu.cn
  • 基金资助:

    国家自然科学基金;南京师范大学“211工程”三期重点学科建设计划

Electrochemical Properties of Covalent Bonded Polyoxometalate/SBA-15 Mesoporous Hybrid Materials

LUO Xiu-Juan, YANG Chun, CHEN Yu   

  1. (Jiangsu Key Laboratory of Biofunctional Materials, College of Chemistry and Material Science, Nanjing Normal University, Nanjing 210097)
  • Received:2010-07-13 Revised:2010-09-01 Published:2010-09-07

Electrochemical behaviors and redox properties of polyoxometalate (POM)/SBA-15 mesoporous hybrid materials, prepared by co-condensation and post-synthesis, were investigated using carbon paste electrodes by cyclic voltammetric measurement. In acetonitrile solution and the range of potentials studied, the cyclic voltammograms of free species in the solution and the same species loaded on mesoporous silica by impregnation showed two one-electron waves corresponding to redox processes of WVI. For the same POM species bonded covalently onto mesoporous silica, however, the current of first wave increased and reduction potentials shifted towards positive direction as compared with the impregnated sample, indicating that these species not only retained the redox property of POM perfectly, but also possessed more intense oxidbillity than the impregnated POM species. The plots of current versus scan rate showed that the redox processes of the hybrid samples were surface-controlled at lower scan rates but diffusion-controlled at higher scan rates. It was also found that the oxidbillity of tungstophosphate was higher than that of tungstosilicate; and the similar electrochemical behaviors were presented for the hybrid samples prepared by both routes.

Key words: electrochemical property, cyclic voltammetry, polyoxometalate, SBA-15, mesoporous hybrid materials

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