Synthesis and Reactivity of 55-Cl-Salicylic Acid-chromium(III) Complexes

Acta Chimica Sinica ›› 2011, Vol. 69 ›› Issue (06): 640-646. Previous Articles Next Articles

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两种55-氯水杨酸铬(III)配合物的合成及反应性研究

南俊霞,刘斌,杨斌盛*

(山西大学分子科学研究所化学生物学与分子工程教育部重点实验室太原 00330000066)

投稿日期:2010-07-24 修回日期:2010-10-20 发布日期:2010-11-25
通讯作者: 杨斌盛 E-mail:yangbs@sxu.edu.cn
基金资助:
CopC铜调控机理的化学研究;水杨酸系列铬配合物的制备、降糖活性及机理研究

Synthesis and Reactivity of 55-Cl-Salicylic Acid-chromium(III) Complexes

NAN Jun-Xia, LIU Bin, YANG Bin-Sheng

(Institute of Molecular Science,, Key Laboratory of Chemical Biology and Molecular Engineering of Education Ministry,, Shanxi University,, Taiyuan 00330000066)

Received:2010-07-24 Revised:2010-10-20 Published:2010-11-25
Contact: BinSheng YANG E-mail:yangbs@sxu.edu.cn

Abstract

Two new chromium(III) complexs [Cr(III)(55-Cl-SA)(en)₂₂]Cl•22CH₃₃OH•22H₂₂O (I) and [Cr(III)(55-Cl-SA)(TETA)]ClO₄₄•H₂₂O (II) (55-Cl-SA=＝55-Cl-salicylic acid, en=＝ethylenediamine, TETA=＝triethylenetetramine) were synthesized and characterized by elemental analysis and X-ray crystallography. The reactivities of those two complexes were compared under different conditions by using UV-Vis and fluorescence spectroscopy. The results indicated that under acid condition, complex II decomposition speed is quicker than complex I|while for the photochemistry reaction, redox reaction in the condition of H₂₂O₂₂ and kinetic activity in the presence of EDTA, the decomposition rate of complex II is slower than complex I.

Key words: chromium complex, 55-Cl-salicylic acid, ethylenediamine, triethylenetetramine, decomposition speed

Cite this article

NAN Jun-Xia, LIU Bin, YANG Bin-Sheng. Synthesis and Reactivity of 55-Cl-Salicylic Acid-chromium(III) Complexes[J]. Acta Chimica Sinica, 2011, 69(06): 640-646.

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[9]	Wang Jun;Fan Damin;Zhang Xiangdong;Ma Rui. Synthesis and Structural Determination of Nine-Coordinate (NH_4)_3 [Y~(III)(ttha)]·5H_2O [J]. Acta Chimica Sinica, 2002, 60(3): 536-540.
[10]	Jia Wenli;Tang Liangfu;Chai Jianfang;Wang Zhihong;Wang Jitao. Synthesis and electrochemical properties of pentacarbonylchromium and tungsten complexes containing pyrazole ligands [J]. Acta Chimica Sinica, 2001, 59(2): 201-206.
[11]	Gao Song;Bai Ou;Yi Tao;Li Junran. A nano-crystalline room-temperature molecular magnet K~0~.~4~5V~1~. ~1~2^ⅡV~0~.~1~9^Ⅲ [Cr(CN)~6](SO~4)~0~.~1~3·4.34H~2O: Coexistence of long range ferrimagnetic ordering and spin glas behavior [J]. Acta Chimica Sinica, 2000, 58(12): 1666-1669.
[12]	NIU SHUYUN;YANG ZHONGZHI;GUO WENSHENG;YANG BING;CHEN YADONG;YANG GUANGDI;ZHANG LIFANG;XU JIQING;HUANG XIAOXING. Synthesis, structure and properties of [Mn(phen)2(H2O)2]2[HOCH2CH2O].4H2O [J]. Acta Chimica Sinica, 1997, 55(8): 786-793.
[13]	LIAO DAIZHENG;SHI JUAN;JIANG ZONGHUI;YAN SHIPING;WANG GENGLIN. Ferromagenetic oxalate-bridged trinuclear Cu(Ⅱ)-Cr(Ⅲ)-Cu(Ⅱ) complexes [J]. Acta Chimica Sinica, 1994, 52(2): 171-175.
[14]	LIU HANXING;LI BAIFU;SUN JIAZHONG. The study of the spectra of complexes Cr(CN) ,Co(CN) , COF by the improved MS-Xαmethod [J]. Acta Chimica Sinica, 1993, 51(7): 652-658.
[15]	YU XIUFANG;JIANG YAQI. The study on the dual-μ~3-O tetranuclear transition metal cluster. I.synthesis and crystal structure of cluster [M~2M'~2O~2(C~2H~5COO)~7 (bipy)~2]·ClO~4(1M=M'=Fe;2M'=Fe M'=C [J]. Acta Chimica Sinica, 1993, 51(6): 579-585.

两种55-氯水杨酸铬(III)配合物的合成及反应性研究

Synthesis and Reactivity of 55-Cl-Salicylic Acid-chromium(III) Complexes

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