Highly Dispersed Pt Nanoparticles Supported on Mesoporous Carbon and Its Electrocatalytic Performance for Ethylene Glycol Oxidation

doi:10.6023/A1106231

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (03): 241-246.DOI: 10.6023/A1106231 Previous Articles Next Articles

Full Papers

高分散的介孔碳载Pt 纳米粒子的制备及其对乙二醇的电催化氧化性能

陈智栋^a,b,c, 陈转霞^a, 汤佳丽^a, 许娟^a,b, 王文昌^a,b, 曹剑瑜^a,b

a 常州大学石油化工学院常州 213164;
b 江苏省太阳能电池与储能技术重点实验室常州 213164;
c 日本阔智电子有限公司大阪 590-0906

投稿日期:2011-06-24 修回日期:2011-08-30 发布日期:2011-11-03
通讯作者: 曹剑瑜 E-mail:jyucao@gmail.com
基金资助:
国家自然科学基金(Nos. 21003015, 21103014)、江苏省企业博士集聚计划基金(No. 2011Z0062)、江苏省高校优势学科建设工程和常州大学科研基金(No.ZMF10020015)资助项目.

Highly Dispersed Pt Nanoparticles Supported on Mesoporous Carbon and Its Electrocatalytic Performance for Ethylene Glycol Oxidation

Chen Zhidong^a,b,c, Chen Zhuanxia^a, Tang Jiali^a, Xu Juan^a,b, Wang Wenchang^a,b, Cao Jianyu^a,b

a School of Petrochemical Engineering, Changzhou University, Changzhou 213164;
b Key Laboratory for Solar Cells and Energy Storage Technology of Jiangsu Province, Changzhou 213164;
c Qualtec Electronics Co. Ltd., Osaka 590-0906, Japan

Received:2011-06-24 Revised:2011-08-30 Published:2011-11-03
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21003015, 21103014), the Natural Science Foundation of Jiangsu Province (No. 2011Z0062), the Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions and the Technology Research Foundation of Changzhou University (No. ZMF10020015).

Mesoporous carbon (MC) with high mesopore content and narrow pore size distribution was prepared using colloidal silica as hard template and Pluronic F127 triblock copolymer as soft template, respectively. Then highly dispersed Pt catalyst supported on MC was achieved by ethylene glycol (EG) reduction method. Electrooxidation behavior of EG on the Pt/MC catalyst electrode in sulfuric solution was investigated using cyclic voltammogram (CV), chronoamperometry, linear sweeping voltammogram (LSV) and electrochemical impedance spectra (EIS) analysis. The experimental results indicate that the electrocatalytic performance of the Pt/MC catalyst for EG oxidation is much higher than that of Pt/XC72R catalyst. EIS analysis further reveals that the electrooxidation reaction of EG on the Pt/MC catalyst electrode has a lower charge-transfer resistance. The higher electrocatalytic activity of the Pt/MC catalyst may be due to the promotion of the MC support with large pore size and uniform mesoporous structure on electron transfer ansfer and mass transfer.

Key words: mesoporous carbon, dual template method, ethylene glycol, electrocatalytic, charge-transfer resistance

Cite this article

Chen Zhidong, Chen Zhuanxia, Tang Jiali, Xu Juan, Wang Wenchang, Cao Jianyu. Highly Dispersed Pt Nanoparticles Supported on Mesoporous Carbon and Its Electrocatalytic Performance for Ethylene Glycol Oxidation[J]. Acta Chimica Sinica, 2012, 70(03): 241-246.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

1 Acres, G. J. K. J. Power Sources 2001, 100, 60.

2 Dyer, C. K. J. Power Sources 2002, 106, 31.

3 Agnolucci, P. Int. J. Hydrogen Energy 2007, 32, 4319.

4 Wang, C. Y. Chem. Rev. 2004, 104, 4727.

5 Kamarudin, S. K.; Daud, W. R. W.; Ho, S. L.; Hasran, U. A. J. Power Sources 2007, 163, 743.

6 Liu, J. Y.; Cao, J. Y.; Wang, Q. H.; Li, X. W.; Zou, Z. Q.; Yang, H. J. Power Sources 2008, 175, 159.

7 Lin, H. L.; Yu, T. L.; Huang, L. N. J. Power Sources 2005, 150, 11.

8 Silva, V. S.; Weisshaar, S.; Reissner, R.; Ruffmann, B.; Vetter, S.; Mendes, A.; Madeira, L. M.; Nunes, S. J. Power Sources 2005, 145, 485.

9 Cao, J. Y.; Chen, M.; Chen, J.; Wang, S. J.; Zou, Z. Q.; Li, Z. L.; Akins, D. L.; Yang, H. Int. J. Hydrogen Energy 2010, 35, 4622.

10 Zhong, Q.-L.; Wang, X.-C.; Zhang, L.; Zhang, X.-H.; Xiang, J.; Ren, B.; Tian, Z.-Q. Acta Chim. Sinica 2003, 61, 1960 (in Chinese). (钟起玲, 王小聪, 章磊, 张小红, 向娟, 任斌, 田中群, 化学学报, 2003, 61, 1960.)

11 Sieben, J. M.; Duarte, M. M. E. Int. J. Hydrogen Energy 2011, 36, 3313.

12 Mench, M. M.; Chance, H. M.; Wang, C. Y. J. Electrochem. Soc. 2004, 151, 1.

13 Serov, A.; Kwak, C. Appl. Catal. B 2010, 97, 2.

14 Qu, W.-L.; Wu, B.; Sun, F.; Gao, Y.; Lu, T.-H.; Liu, C.-P.; Xing, W. Acta Chim. Sinica 2005, 63, 1565 (in Chinese). (曲微丽, 邬冰, 孙芳, 高颖, 陆天虹, 刘长鹏, 邢巍, 化学学报, 2005, 63, 1565.)

15 Selvaraj, V.; Vinoba, M.; Alagar, M. J. Colloid Interface Sci. 2008, 322, 537.

16 Qu, W.-L.; Wu, B.; Sun, F.; Gao, Y.; Lu, T.-H.; Liu, C.-P.; Xing, W. Acta Phys.-Chim. Sinica 2005, 21, 804 (in Chinese). (曲微丽, 邬冰, 孙芳, 高颖, 陆天虹, 刘长鹏, 邢巍, 物理化学学报, 2005, 21, 804.)

17 Jin, C. C.; Sun, C.; Dong, R. L.; Chen, Z. D. Electrochim. Acta 2010, 56, 321.

18 Chetty, R.; Scott, K. J. Appl. Electrochem. 2007, 37, 1077.

19 Zhao, G. W.; He, J. P.; Zhang, C. X.; Zhou, J. H.; Chen, X.; Wang, T. J. Phys. Chem. C 2008, 112, 1028.

20 Stober, W.; Fink, A. J. Colloid Interface Sci. 1968, 26, 62.

21 Meng, Y.; Gu, D.; Zhang, F. Q.; Shi, Y. F.; Yang, H. F.; Li, Z.; Yu, C. Z.; Tu, B.; Zhao, D. Y. Angew. Chem. Int. Ed. 2005, 44, 7053.

22 Fang, B. Z.; Kim, M.; Hwang, S.; Yu, J. S. Carbon 2008, 46, 878.

23 Radmilovic, V.; Gasteiger, H. A.; Ross, P. N. J. J. Catal. 1995, 154, 98.

24 Antolini, E.; Cardellini, F. J. J. Alloys Compd. 2001, 315, 118.

25 Liu, C.-Y.; Xu, B.; Tang, Y.-W.; Cao, G.-P.; Yang, Y.-S.; Lu, T.-H. Acta Phys.-Chim. Sinica 2011, 27, 604 (in Chinese). (刘春艳, 徐斌, 唐亚文, 曹高萍, 杨裕生, 陆天虹, 物理化学学报, 2011, 27, 604.)

26 Shim, J.-W.; Park, S.-J.; Ryu, S.-K. Carbon 2001, 39, 1635.

27 Fu, Q.; Li, W.-X.; Yao, Y.-X.; Liu, H.-Y.; Su, H.-Y.; Ma, D.; Gu, X.-K.; Chen, L.-M.; Wang, Z.; Zhang, H.; Wang, B.; Bao, X.-H. Science 2010, 328, 1141.

28 Yang, S.-D.; Zhang, X.-G.; Huang, J.-S.; Sun, J.-Y. Acta Phys.-Chim. Sinica 2007, 23, 1224 (in Chinese). (杨苏东, 张校刚, 黄建书, 孙景玉, 物理化学学报, 2007, 23, 1224.)

29 Ciureanu, M.; Roberge, R. J. Phys. Chem. B 2001, 105, 3531.

[1]	Zhenhong Yang, Xiaojuan Gan, Shuzhe Wang, Junyuan Duan, Tianyou Zhai, Youwen Liu. Preparation of Metallic Ni₃N Nanoparticles and Its Electrooxidation Performance for Ethylene Glycol^★ [J]. Acta Chimica Sinica, 2023, 81(11): 1471-1477.
[2]	Zeyang Li, Yusen Yang, Min Wei. Structural Design and Performance of Electrocatalysts for Carbon Dioxide Reduction: A Review [J]. Acta Chimica Sinica, 2022, 80(2): 199-213.
[3]	Chunhui Mu, Yixin Zhang, Wei Kou, Lianbin Xu. Nickel-Nitrogen-Doped Ordered Macro-/Mesoporous Carbon Supported Ag Nanoparticles for Efficient Electrocatalytic CO₂ Reduction [J]. Acta Chimica Sinica, 2021, 79(7): 925-931.
[4]	Wang Wenbin, Wen Qunlei, Liu Youwen, Zhai Tianyou. Research Progress of Surface and Interface Chemistry Regulate Two-dimensional Materials for Electrocatalytic Biomass Conversion [J]. Acta Chimica Sinica, 2020, 78(11): 1185-1199.
[5]	Wei Junhao, Cai Wanhao, Cui Shuxun. Single-chain Elasticity of Poly(ethylene glycol) in High Vacuum [J]. Acta Chim. Sinica, 2019, 77(2): 189-194.
[6]	Niu Dongfang, Ding Yong, Ma Zhixing, Wang Minghui, Liu Zhou, Zhang Bowen, Zhang Xinsheng. Effects of Surface Modification of Carbon Nanofibers on Their Electro- catalytic Activity for Hydrogen Evolution Reaction of Water Electrolysis [J]. Acta Chim. Sinica, 2015, 73(7): 729-734.
[7]	Han Ruobing, Lu Shan, Wang Yanjie, Zhang Xuehua, Wu Qiang, He Tao. Application of SO₄^- and I^- co-Doped Polyaniline Counter Electrode in Dye-sensitized Solar Cells [J]. Acta Chim. Sinica, 2015, 73(10): 1061-1068.
[8]	Zhang Guangmeng, Yang Jiping, Chen Gong. Self-assembly of Tetraaniline-PEG-Tetraaniline Block Copolymer Thin Films [J]. Acta Chimica Sinica, 2014, 72(1): 83-88.
[9]	Zhang Shujin, Zheng Yixiong, Yuan Linshan, Yang Weihua. Electrocatalytic Oxidation of Glucose on Highly Dispersed Ni-B/Nanoporous Cu Amorphous Alloy Electrode [J]. Acta Chimica Sinica, 2013, 71(12): 1676-1682.
[10]	Lu Zhenjiang, Xu Maowen, Bao Shujuan, Chai Hui. Preparation and Oxygen Reduction Performance of GNs-MnO₂ composite [J]. Acta Chimica Sinica, 2013, 71(06): 957-961.
[11]	Wang Huying, Xu Jinfeng, Jing Hua, Zhang Jun, Li Peiqiang, Lu Fusui. Honeycomb Cupric Oxide and Hematite Nanotubes Synergism Photoelectro-reduction CO₂ [J]. Acta Chimica Sinica, 2013, 71(06): 941-946.
[12]	Sun He, Li Qunyan, Wang Xuewei, Wei Qi, Nie Zuoren. Rapid Aqueous Synthesis of Mesoporous Carbon and Their HRP Immobilization Performance [J]. Acta Chimica Sinica, 2013, 71(04): 619-624.
[13]	Zhang Xiaoqing, Zeng Meigui, Li Shuping. Influence of Different Solvents on the Property of Methotrexate/Layered Double Hydroxides [J]. Acta Chimica Sinica, 2013, 71(02): 246-254.
[14]	Lu Weitao, Yang Jiping. Synthesis and Characterization of Tetraaniline-Polyethylene Glycol Block and Star-shaped Copolymers [J]. Acta Chimica Sinica, 2013, 71(01): 121-125.
[15]	Tan Xuecai, Wang Lin, Li Pengfei, Gong Qi, Liu Li, Zhao Dandan, Lei Fuhou, Huang Zaiyin. Electrochemical Sensor for the Determination of Theophylline Based on Molecularly Imprinted Polymer with Ethylene Glycol Maleic Rosinate Acrylate as Cross-linker [J]. Acta Chimica Sinica, 2012, 70(9): 1088-1094.

高分散的介孔碳载Pt 纳米粒子的制备及其对乙二醇的电催化氧化性能

Highly Dispersed Pt Nanoparticles Supported on Mesoporous Carbon and Its Electrocatalytic Performance for Ethylene Glycol Oxidation

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments