A Series of 2D Coordination Polymers Based on Unprecedented Linear Tetranuclear Units Bridged by the Azido Anion: Syntheses, Crystal Structures and Magnetic Properties

doi:10.6023/A13010121

Acta Chimica Sinica ›› 2013, Vol. 71 ›› Issue (05): 755-760.DOI: 10.6023/A13010121 Previous Articles Next Articles

Special Issue: 纪念南开大学化学学科创建100周年

Article

基于线性叠氮四核单元的系列二维化合物: 合成, 晶体结构及磁性

李佐习, 杨乾, 李立存, 胡同亮, 卜显和

南开大学化学系金属与分子基材料化学天津市重点实验室天津 300071

投稿日期:2013-01-24 发布日期:2013-03-26
通讯作者: 胡同亮,tlhu@nankai.edu.cn E-mail:tlhu@nankai.edu.cn
基金资助:
项目受国家自然科学基金(Nos. 21031002, 51073079)和天津市自然科学基金(No. 11JCYBJC04100)资助.

A Series of 2D Coordination Polymers Based on Unprecedented Linear Tetranuclear Units Bridged by the Azido Anion: Syntheses, Crystal Structures and Magnetic Properties

Li Zuoxi, Yang Qian, Li Licun, Hu Tongliang, Bu Xianhe

Department of Chemistry, and Tianjin Key Laboratory of Metal & Molecule-based Material Chemistry, Nankai University, Tianjin 300071

Received:2013-01-24 Published:2013-03-26
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21031002, 51073079) and the Natural Science Fund of Tianjin, China (No. 11JCYBJC04100).

1. A Series of 2D Coordination Polymers Based on Unprecedented Linear Tetranuclear Units Bridged by the Azido Anion: Syntheses, Crystal Structures and Magnetic Properties.PDF(88KB)

Abstract

Sparked by the strategy of molecular magnets, three magnetic coordination polymers, [Co₂(N₃)₄(L)_2.5]_∞ (1), [Ni₂(N₃)₃(NO₃)(L)_2.5]_∞ (2) and [Mn₂(N₃)₄(L)_2.5]_∞ (3) (L=4,4'-bis(imidazol-1-yl)biphenyl), have been synthesized by employing azide as the coupling carrier and a rod-like ligand L as the magnetic insulator. Structural analysis indicates that complexes 1～3 are iso-structural, and illustrate a 2D (4,4) layer based on unprecedented linear tetranuclear units bridged by the EO-azido ions. Their magnetic measurements revealed that complexes 1～3 all present the ferromagnetic (FM) coupling, which was due to the EO-azido linker. The corresponding exchange coupling constants have been estimated by fitting the experimental data, which confirmed the above magneto-structural correlations.

Key words: coordination polymer, rod-like ligand, linear tetranuclear cluster, magnetic property

Cite this article

Li Zuoxi, Yang Qian, Li Licun, Hu Tongliang, Bu Xianhe. A Series of 2D Coordination Polymers Based on Unprecedented Linear Tetranuclear Units Bridged by the Azido Anion: Syntheses, Crystal Structures and Magnetic Properties[J]. Acta Chimica Sinica, 2013, 71(05): 755-760.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Toma, L. M.; Ruiz-Pérez, C.; Pasán, J.; Wernsdorfer, W.; Lloret, F.; Julve, M. J. Am. Chem. Soc. 2012, 134, 15265.
[2] Kurmoo, M. Chem. Soc. Rev. 2009, 38,1353.
[3] Bagai, R.; Christou, G. Chem. Soc. Rev. 2009, 38, 1011.
[4] Aromí, G.; Aguilà, D.; Gamez, P.; Luis, F.; Roubeau, O. Chem. Soc. Rev. 2012, 41, 537.
[5] Sanvito, S. Chem. Soc. Rev. 2011, 40, 3336.
[6] Leng, J.; Liu, J.; Tong, M. Chem. Commun. 2012, 48, 5286.
[7] Liu, R.; Li, L.; Wang, X.; Yang, P.; Wang, C.; Liao, D.; Sutter, J. Chem. Commun. 2010, 46, 2566.
[8] Jiang, S. D.; Wang, B. W.; Sun, H. L.; Wang, Z. M.; Gao, S. J. Am. Chem. Soc. 2011, 133, 4730.
[9] Yang, E. C.; Liu, Z. Y.; Wu, X. Y.; Zhao, X. J. Chem. Commun. 2011, 47, 8629.
[10] Yao, M. X.; Zheng, Q.; Cai, X. M.; Li, Y. Z.; Song, Y.; Zuo, J. L. Inorg. Chem. 2012, 51, 2140.
[11] Miller, J. S. Chem. Soc. Rev. 2011, 40, 3266.
[12] Xu, G. C.; Zhang, W.; Ma, X. M.; Chen, Y. H.; Zhang, L.; Cai, H. L.; Wang, Z. M.; Xiong, R. G.; Gao, S. J. Am. Chem. Soc. 2011, 133, 14948.
[13] Huang, Y. G.; Jiang, F. L.; Hong, M. C. Coord. Chem. Rev. 2009, 253, 2814.
[14] Zeng, Y. F.; Hu, X.; Liu, F. C.; Bu, X. H. Chem. Soc. Rev. 2009, 38, 469.
[15] Ribas, J.; Escuer, A.; Monfort, M.; Vicente, R.; Cortés, R.; Lezama, L.; Rojo, T. Coord. Chem. Rev. 1999, 193～195, 1027.
[16] Zhao, J. P.; Hu, B. W.; Yang, Q.; Liu, F. C.; Hu, T. L.; Bu, X. H. Chin. Sci. Bull. 2009, 54, 4303.
[17] Zhang, X. F.; Yang, Q.; Zhao, J. P.; Hu, T. L.; Chang, Z.; Bu, X. H. Sci. China Chem. 2011, 54, 1446.
[18] Gao, E. Q.; Liu, P. P.; Wang, Y. Q.; Yue, Q.; Wang, Q. L. Chem. Eur. J. 2009, 15, 1217.
[19] Su, Z.; Bai, Z. S.; Fan, J.; Xu, J.; Sun, W. Y. Cryst. Growth Des. 2009, 9, 5190.
[20] Li, Z. X.; Zhao, J. P.; San?udo, E. C.; Ma, H.; Pan, Z. D.; Zeng, Y. F.; Bu, X. H. Inorg. Chem. 2009, 48, 11601.
[21] Li, Z. X.; Ma, H.; Chen, S. L.; Pan, Z. D.; Zeng, Y. F.; Wang, X. L.; Bu, X. H. Dalton Trans. 2011, 40, 31.
[22] Fan, J.; Hanson, B. E. Chem. Commun. 2005, 2327.
[23] SAINT Software Reference Manual; Bruker AXS: Madison, WI, 1998.
[24] Sheldrick, G. M.; SHELXTL NT Version 5.1, University of Göttingen, Germany, 1997.
[25] Wang, X. L.; Mu, B.; Lin, H. Y.; Yang, S.; Liu, G. C.; Tian, A. X.; Zhang, J. W. Dalton Trans. 2012, 41, 11074.
[26] Li, Z. X.; Zeng, Y. F.; Ma, H.; Bu, X. H. Chem. Commun. 2010, 46, 8540.
[27] Li, C. P.; Chen, J.; Yu, Q.; Du, M. Cryst. Growth Des. 2010, 10, 1623.
[28] Yang, Q.; Zhao, J. P.; Song, W. C.; Bu, X. H. Dalton Trans. 2012, 41, 6272.
[29] Zeng, M. H.; Yao, M. X.; Liang, H.; Zhang, W. X.; Chen, X. M. Angew. Chem., Int. Ed. 2007, 46, 1832.
[30] Kambe, K. J. Phys. Soc. Jpn. 1950, 5, 48.
[31] Borrás-Almenar, J. J.; Clemente-Juan, J. M.; Coronado, E.; Tsukerblat, B. S. J. Comput. Chem. 2001, 22, 985.
[32] Zhou, Y. L.; Zeng, M. H.; Liu, X. C.; Liang, H.; Kurmo, M. Chem. Eur. J. 2011, 17, 14084.
[33] Fellah, F. Z. C.; Costes, J. P.; Dahan, F.; Duhayon, C.; Novitchi, G.; Tuchagues, J. P.; Vendier, L. Inorg. Chem. 2008, 47, 6444.
[34] Ruiz, E.; Cano, J.; Alvarez, S.; Alemany, P. J. Am. Chem. Soc. 1998, 120, 11122.
[35] Mialane, P.; Dolbecq, A.; Rivière, E.; Marrot, J.; Sècheresse, F. Angew. Chem., Int. Ed. 2004, 43, 2274.
[36] Yang, P. P.; Song, X. Y.; Liu, R. N.; Li, L. C.; Liao, D. Z. Dalton Trans. 2010, 39, 6285.

基于线性叠氮四核单元的系列二维化合物: 合成, 晶体结构及磁性

A Series of 2D Coordination Polymers Based on Unprecedented Linear Tetranuclear Units Bridged by the Azido Anion: Syntheses, Crystal Structures and Magnetic Properties

PDF

Supporting Info.

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles 0

Metrics

Comments

[1]	Yong Li, Xiao-Yan Wang, Yong Tang. Coordination Polymerization of α,ω-Diolefin: the Regulation of Polymer Microstructure by Catalyst [J]. Acta Chimica Sinica, 2021, 79(11): 1320-1330.
[2]	Wang Qin, Nie Zhou, Hu Yufang, Yao Shouzhuo. Electrochemical Assay for Acetylcholinesterase Activity Detection Based on Unique Electro-catalytic Activity of Cu(II)-thiol Coordination Polymer [J]. Acta Chim. Sinica, 2017, 75(11): 1109-1114.
[3]	Ni Chunyan, Chen Yang, Li Duanxiu, Ren Zhigang, Li Hongxi, Sun Zhenrong, Lang Jianping. Halide-Directed Synthesis of Coordination Polymers [Hg₂X₄(ppt)]_n (X=I and Br, ppt=1-(4-Pyridyl)-pyridinium-4-thiolate) with Different One-Dimensional Chain Structures and Third-Order Nonlinear Optical Properties [J]. Acta Chimica Sinica, 2013, 71(06): 906-912.
[4]	Lin Zujin, Lin Xi, Cao Rong. Construction of Two Octahedral Cage-based Metal-organic Frameworks [J]. Acta Chimica Sinica, 2012, 70(19): 2012-2015.
[5]	YANG Shu-Ping, HAN Li-Jun, WANG Da-Qi, PAN Yan, YU Zhi-Qun, YE Hai-Yan. Solvothermal Synthesis, Crystal Structure of a 1D Coordination Polymer [Er(CCA)₃(H₂O)₂]_n•2nH₂O (HCCA＝Coumarin-3-Carboxylic Acid) and the Interaction between the Polymer and Bovine Serum Albumin (BSA) [J]. Acta Chimica Sinica, 2011, 69(19): 2319-2327.
[6]	. tructure Stability and Magnetic Properties of Pt_nNi_m(n＋m＝7, n, m≠0) Clusters [J]. Acta Chimica Sinica, 2011, 69(17): 2063-2069.
[7]	LI Zhi-Min, ZHANG Guo-Tao, ZHANG Tong-Lai, ZHANG Jian-Guo, YANG Li, ZHOU Zun-Ning, QI Shu-Yuan, YU Kai-Bei, ZHAO Feng-Qi, YI Jian-Hua, XU Si-Yu, GAO Hong-Xu. Synthesis, Structural Investigation and Properties of A Novel Energetic Coordination Polymer [Pb(tza)₂]_n [J]. Acta Chimica Sinica, 2011, 69(10): 1253-1258.
[8]	YAN Xiao-Bing, CHEN Xing-Guo, QIN Jin-Gui. Synthesis and Magnetic Properties of New Layered Ni_xMn_{1－xPS₃ and Their Intercalation Compounds} [J]. Acta Chimica Sinica, 2011, 69(08): 1017-1023.
[9]	XIANG Jun, SHEN Xiang-Qian, CHU Yan-Qiu, ZHOU Guang-Zhen, GUO Yin-Tao. Effect of Calcination Temperature on Microstructure and Magnetic Properties of Ni_0.3Cu_0.2Zn_0.5Fe₂O₄ Nanofibers [J]. Acta Chimica Sinica, 2010, 68(16): 1609-1615.
[10]	LI Qiao-Ling, CHANG Chuan-Bo. The Preparation and Magnetic Properties of Acicular Nano-Ni_xZn_1－xFe₂O₄ [J]. Acta Chimica Sinica, 2010, 68(14): 1385-1390.
[11]	YIN Wei-Feng, OU Zhi-Ze , GAO Yun-Yan-*, HAO Ping, GUO Chuang-Long, WANG Zhong-Li. Interaction of 1,4-Dihydroxyanthraquinone and Its Yttrium Coordination Polymer with DNA [J]. Acta Chimica Sinica, 2010, 68(14): 1343-1348.
[12]	LU Run-Qin, CHEN Ying-Ying, ZHOU Hu, YUAN Ai-Hua. 2O)₂[Ni(CN)₄]•xH₂O [J]. Acta Chimica Sinica, 2010, 68(12): 1199-1204.
[13]	LIU Tian-Qing, SONG Li-Na. Preparation and Properties of FeOOH-gelatin Complex Nano-particles [J]. Acta Chimica Sinica, 2010, 68(11): 1057-1062.
[14]	LI Liang-Chao, HAO Bin, XIANG Chen, TONG Guo-Xiu, CHEN Ke-Yu. Preparation and Electrical/Magnetic Properties of Polypyrrole/Cu-Zn Ferrites Doped with Gd Nanocomposites [J]. Acta Chimica Sinica, 2010, 68(06): 583-589.
[15]	. Preparation and Electromagnetic Properties of Composite Polyaniline/Polyacrylamide/Zn0.4Ni0.5Cu0.1Fe2O4 [J]. Acta Chimica Sinica, 2009, 67(12): 1395-1400.