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Acta Chimica Sinica ›› 1980, Vol. 38 ›› Issue (5): 451-458. Previous Articles Next Articles
甘立宪, 郭广忠, 徐锦文
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GAN LI-XIAN, GUO GUANG-ZHONG, XU JIN-WEN
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In the search of potent precocene analogs possessing antijuvenile hormone activity,some new chromeno derivatives were synthesized.In the presence of polyphosphorio acid,the pyrogallol monomethyl ether 4 reaoted with β,β-dimethylacrylio acid(5) to afford the ohromanone(6),whioh was reduced with lithium aluminum hydride in ether,followed by the acid-catalysed dehydration to give the desired product 8.'hreatment of 8 with dimethyl sulfate,propargyl bromide and methyl isocyanate gave the compounds 10,11 and 12 respectively.The biological tests of these four compounds(8,10,11 and 12) will be reported elsewhere.
GAN LI-XIAN, GUO GUANG-ZHONG, XU JIN-WEN. THE SYNTHESIS OF THE INSECT ANTIJUVENILE HORMONE ANALOGS[J]. Acta Chimica Sinica, 1980, 38(5): 451-458.
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