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Acta Chimica Sinica ›› 1979, Vol. 37 ›› Issue (3): 201-206. Previous Articles     Next Articles

(3,4),(8,9)-双环氧-内式-三环[5.2.1.02,6]癸烷在丙酮溶液中同氯化氢的开环反应

邓先模, 黄志镗   

  1. 中国科学院化学研究所 北京
  • 投稿日期:1978-03-20 发布日期:2013-06-03

THE RING OPENING REACTION OF (3,4), (8,9)-DIEPOXYENDOTRICYCLO [5.2.1.02,6] DECANE WITH HYDROGEN CHLORIDE IN ACETONE

DENG XIAN-MU, HUANG ZHI-TANG   

  1. Institute of Chemistry, Academia Sinica, Beijing
  • Received:1978-03-20 Published:2013-06-03

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Tho rirg opening reaotion of (3, 4),(8, 9)-diepogyendotrioyolo [5.2.1.02,6] decane and its exo-isomer and some related model oomponnds with hydrogen ohloride in acetone was studied.The results indioated that the epoxy group on oyolopentane ring was morn reaotive towards suoh ring opening agent than that on the bioyolo [2.2.1] hoptane ring.