SIOC 中文
ACS
Adv search

Acta Chimica Sinica ›› 1966, Vol. 32 ›› Issue (2): 162-168. Previous Articles     Next Articles

硫氰酸根络合物的晶体化学——Ⅰ.Cu(NH3)2Ag(SCN)3的晶体结构

黄金陵1, 李建民1,2, 卢嘉锡1   

  1. 1. 中国科学院华东物质结构研究所, 福州大学化学化工系;
    2. 华东自动化元件和仪表研究所
  • 投稿日期:1964-12-03 发布日期:2013-06-03

THE CRYSTAL CHEMISTRY OF THIOCYANATE-LIGATED COMPOUNDS OF TRANSITION METALS Ⅰ. THE CRYSTAL STRUCTURE OF DI-AMMINE COMPLEX OF COPPER (Ⅱ) SILVER (Ⅰ) TRITHIOCYANATE Cu(NH3)2Ag(SCN)3

HUANG JIN-LING1, LI JIEN-MING1,2, LU JIA-XI(CHIA-SI Lu)1   

  1. 1. East China Institute of the Structure of Matter, Academia Sinica;
    2. Department of Chemistry and Chemical Engineering, Foochow University
  • Received:1964-12-03 Published:2013-06-03

PDF

581

An X-ray examination of the deep-green-coloured, hexagonal-prismatic or hexagonalbipyramidal-shaped crystals of the di-ammine complex of copper (Ⅱ) silver (I) trithiocyanate, obtained on mixing CuSO4 and K2Ag(SCN)3 in a dilute ammoniacal solution, gives the following crystallographic data: a=9.22Å,c=7.38Å, containing two Cu(NH3)2Ag (SCN)3 per unit cell (ρobs=2.308g/cm3, ρealc=2.319g/cm3).