Acta Chimica Sinica ›› 1964, Vol. 30 ›› Issue (3): 241-249.     Next Articles

芳香族化合物与分子氧间的电子转移光谱及其与芳香族化合物的电子激发和光致氧化的关系

吴学周, 朱晋錩, 何迪潔   

  1. 中国科学院应用化学研究所
  • 投稿日期:1963-01-17 修回日期:1963-07-29 发布日期:2013-06-03

THE CHARGE-TRANSFER SPECTRA BETWEEN ORGANIC COMPOUNDS AND MOLECULAR OXYGEN,AND THE PHOTOCHEMICAL AUTOXIDATION OF SOME ORGANIC COMPOUNDS

WOO SHO-CHOW, CHU TSIN-CHANG, HO DE-GIEH   

  1. Institute of Applied Chemistry, Academia Sinica
  • Received:1963-01-17 Revised:1963-07-29 Published:2013-06-03

The UV absorption spectra of the mixtures of aromatic compounds-benzene, toluene, isobutylbenzene, p-xylene, xylene (mixture), mesitylene, aniline, benzaldehyde, and anthracene with molecular oxygen have been investigated.It was found that in agreement with the observation of Evans, charge-transfer spectra were observed for all of the mixtures, with the exception of those of anthracene and of benzaldehyde.The frequenties of these charge-transfer spectra vary linearly with the ionization potentials of the organic compounds.