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Acta Chimica Sinica ›› 1964, Vol. 30 ›› Issue (3): 316-324. Previous Articles Next Articles
蒋明谦, 曹怡, 汪文石
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CHIANG MING-CHIEN, TSAO I, WANG WEN-SHI
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In the presence of a three-component catalyst (tri-n-butylamine, tetramethyl-ethylenediamine, and cuprous chloride), the addition reaction of a series of silanes (trichlorosilane, phenyldichlorosilane, methyldichlorosilane, diphenylchlorosilane, methylphenylchlorosilane, diphenylchlorosilane, methylphenylchlorosilane, diethylchlorosilane and, triethylsilane) with acrylonitrile has been studied.Under the same reaction conditions, a quantitative tomparison of the reactivities of these silanes revealed that the percentages of yields for the addition give a "sigmoid" curve when plotted versus the corresponding inductive indices for the substituted atoms or groups in the silane molecules.
CHIANG MING-CHIEN, TSAO I, WANG WEN-SHI. Ⅳ.THE INFLUENCE OF THE STRUCTURES OF HYDROSILANES AND OLEFINIC NITRILES ON THE ADDITION REACTION BETWEEN THEM[J]. Acta Chimica Sinica, 1964, 30(3): 316-324.
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