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Acta Chimica Sinica ›› 1963, Vol. 29 ›› Issue (3): 166-172. Previous Articles     Next Articles

内醚糖——Ⅶ.关于2, 3-内醚-D-阿罗糖吡喃甙转化为3, 6-内醚-D-葡萄糖吡喃甙的实驗証据

張滂1, 胡昌明2   

  1. 1. 北京大学化学系;
    2. 中国科学院应用化学研究所
  • 投稿日期:1962-05-30 发布日期:2013-06-03

EXPERIMENTAL EVIDENCE CONCERNING THE TRANSFORMATION OF 2, 3-ANHYDRO-D-ALLOPYRANOSIDE TO 3, 6-ANHYDRO-D-GLUCOPYRANOSIDE

P. CHANG1, HU CHAN-MING2   

  1. 1. Department of Chemistry, Peking University;
    2. Institute of Applied Chemistry, Academia Sinica
  • Received:1962-05-30 Published:2013-06-03

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Ohle and his coworkers suggested that a 3,6-anhydrohexoside can be formed from 2,3-anhydrohexoside in alkaline media if the 2,3-anhydro ring is disposed in Haworth's perspective formula such that it is in the opposite side to the C5-CH2OH side chain. It is obvious that the transformation involves an intramolecular SN2 mechanism, but experimental evidence is quite limited.