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Acta Chimica Sinica ›› 1957, Vol. 23 ›› Issue (6): 486-491. Previous Articles Next Articles
高鸿1, 张祖训1, 蒋雄圖2, 胡秀仁1
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KAO HUNG1, CHANG TSOW-SHIEN1, CHIANG HSTUNG-TU2, HU HSIU-JEN1
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A series of experiments were carried out to verify the basic principles of "inverse polarography" suggested by Hickling,Maxwell and Shennan.Results lead to conclusions quite different from those of tho above workers.In the case of cadmium amalgam electrodes,within the amalgam,the diffusion of electro-active metal from interior to amalgam-solution interface obeys the general equation of linear diffusionit=nFAD1/2C(1/(√πt)Anodic half-wave potentials obtained from C-V curves have a definite constant value indepedent Of amalgam concentration.
KAO HUNG, CHANG TSOW-SHIEN, CHIANG HSTUNG-TU, HU HSIU-JEN. STUDIES ON VOLTAMMETRY WITH STATIONARY AMALGAM ELECTRODES Ⅰ. CADMIUM AMALGAM ELECTRODES[J]. Acta Chimica Sinica, 1957, 23(6): 486-491.
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