Acta Chimica Sinica ›› 1956, Vol. 22 ›› Issue (5): 409-413. Previous Articles     Next Articles

sinodiosgenin的结构

黄维垣1, 陈毓群1, 朱任宏2   

  1. 1. 中国科学院有机化学研究所;
    2. 中国科学院药物研究所
  • 投稿日期:1956-03-13 发布日期:2013-06-04

STRUCTURE OF SINODIOSGENIN

HUANG WEI-YUAN1, CHEN YUH-CHENG1, CHU JEN-HUNG2   

  1. 1. Institute of Organic Chemistry, Academic Sinica;
    2. Institute of Materia Medica, Academic Sinica
  • Received:1956-03-13 Published:2013-06-04

Sinodiosgenin isolated from dioscorea saciva has been identified as diosgenin β-D-glucopyranoside and is probably identical with trillin,which was considered as "diosgenin α-D-glucoside" by Marker.However,evidences the methods of synthesis and comparison of molecular rotation data show that the glucosidic linkage should be ofβinstead of the previously assigned α-configuration.