Effect of Mo on the Structure and Catalytic Behavior of the Rapidly Quenched Skeletal Ni-Mo Catalysts

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (14): 1281-1286. Previous Articles Next Articles

Mo对猝冷Ni-Mo骨架催化剂结构和催化性能的影响

胡华荣¹, 王友臻¹, 乔明华¹, 范康年¹, 宗保宁², 张晓昕², 李和兴³

1. 复旦大学化学系, 上海市分子催化和创新材料重点实验室, 上海, 200433;
2. 石油化工科学研究院, 北京, 100083;
3. 上海师范大学化学系, 上海, 200233

投稿日期:2003-08-12 修回日期:2004-03-23 发布日期:2014-02-17
通讯作者: 范康年,E-mail:knfan@fudan.edu.cn;乔明华,E-mail:mhqiao@fudan.edu.cn E-mail:knfan@fudan.edu.cn;mhqiao@fudan.edu.cn
基金资助:
"973"国家重点基础研究发展规划(No.G2000048009)、国家自然科学基金(Nos.20203004,20073008)和上海市自然科学基金(No.02ZA14006)资助项目.

Effect of Mo on the Structure and Catalytic Behavior of the Rapidly Quenched Skeletal Ni-Mo Catalysts

HU Hua-Rong¹, WANG You-Zhen¹, QIAO Ming-Hua¹, FAN Kang-Nian¹, ZONG Bao-Ning², ZHANG Xiao-Xin², LI He-Xing³

1. Shanghai Key Laboratory of Molecular Catalysis & Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433;
2. Research Institute of Petroleum Processing, Beijing 100083;
3. Department of Chemistry, Shanghai Normal University, Shanghai 200233

Received:2003-08-12 Revised:2004-03-23 Published:2014-02-17

Abstract

A series of rapidly quenched skeletal Ni-Mo catalysts with different Mo contents were prepared by alkali leaching of Ni-Mo-Al alloys derived from the single-roller melt-spinning method.It was revealed that the addition of Mo not only alters the phase compositions of the Ni-Mo-Al alloys, but also has pronounced influence on the physical characters of the leached Ni-Mo catalysts.In liquid phase hydrogenation of 2-ethylanthraquinone, it was found that Mo can accelerate the hydrogenation while depress the formation of the degradation products.The yield of H₂O₂ reaches as high as ca.100% at a Mo content of 2.47 wt% in the catalyst.The positive effect of Mo on the catalytic behavior was rationalized in terms of the nickel crystallite size, the population of the surface hydrogen species, and the chemical states of Mo.

Key words: rapidly quenched alloy, Ni-Mo-Al,Ni-Mo, 2-ethylanthraquinone, H₂O₂

Cite this article

HU Hua-Rong, WANG You-Zhen, QIAO Ming-Hua, FAN Kang-Nian, ZONG Bao-Ning, ZHANG Xiao-Xin, LI He-Xing. Effect of Mo on the Structure and Catalytic Behavior of the Rapidly Quenched Skeletal Ni-Mo Catalysts[J]. Acta Chimica Sinica, 2004, 62(14): 1281-1286.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Robertson, S. D.; Anderson, R. B. J. Catal. 1976, 41,405.
[2] Lee, H. K.; Jung, E. E.; Lee, J. S. Mater. Chem. Phys.1998, 55, 89.
[3] Masson, J.; Cividino, P.; Court, J. Appl. Catal. A 1997,161, 191.
[4] Montgomery, S. R. In Catalysis of Organic Reactions, Marcel Dekker, New York, 1981, p. 393.
[5] Gallezot, P.; Cerino, P. J.; Blanc, B.; Fleche, G.; Fuertes, P. J. Catal. 1994, 146, 93.
[6] Gros, J.; Hamer-Thibault, S.; Joud, J. C. J. Mater. Sci. 1989, 24, 2987.
[7] Liu, B.; Qiao, M. H.; Deng, J. F.; Fan, K. N.; Zhang, X. X.; Zong, B. N. J. Catal. 2001, 204, 512.
[8] Hu, H.-R.; Pei, Y.; He, Y.-G.; Xie, S.-H.; Jiang, H.W.; Fan, K.-N.; Qiao, M.-H.; Zong, B.-N.; Zhang, X.-X. J. Fudan Univ. 2002, 41,466 (in Chinese).(胡华荣,裴燕,何永根,谢颂海,姜慧文,范康年,乔明华,宗保宁,张晓昕,复旦大学学报,2002,41,466.)
[9] Wang, D.-L.; Wang, X.-K.; Ba, F.-H.; Shen, N.-F. J.Zhengzhou Univ. Technol. 2000, 21, 37 (in Chinese).(王东立,王西科,巴发海,沈宁福,郑州工业大学学报,2000, 21, 37. )
[10] Lei, H.; Song, Z.; Tan, D.-L.; Bao, X.-H.; Mu, X.-H.; Zong, B.-N.; Min, E.-Z. Chem. J. Chin. Univ. 2002, 23,2121 (in Chinese).(雷浩,宋真,谭大力,包信和,慕旭宏,宗保宁,闵恩泽,高等学校化学学报,2002,23,2121.)
[11] Zhang, H.-F.; Li, J.; Song, Q.-H.; Wang, J.-T. Mater. Sci. Prog. 1993, 7, 225 (in Chinese).(张海峰,李杰,宋启洪,王景唐,材料科学进展,1993,7,225. )
[12] Lu, Z.-L.; Wang, R.; Ke, J.; Chen, H.; Mu, X.-H.; Zong, B.-N. Chin. J. Catal. 1997, 18, 110 (in Chinese).(陆致龙,王蓉,柯俊,陈桦,慕旭宏,宗保宁,催化学报,1997,18,110.)
[13] Chen, X.-M.; Zhang, G.-S.; Wang, X.-K.; Shen, N.-F. J. Zhengzhou Univ. Technol. 1999, 20, 57 (in Chinese).(陈向明,张国胜,王西科,沈宁福,郑州工业大学学报,1999,20,57.)
[14] Highfield, J. G.; Oguro, K.; Grushko, B. Electrochim. Acta 2001, 47, 465.
[15] Taylor, A.; Doyle, N. J. J. Appl. Crystallogr. 1972, 5,210.
[16] Liu, B. Ph. D. Dissertation, Fudan University, Shanghai, 2003(in Chinese).(刘波,博士学位论文,复旦大学,上海,2003.)
[17] Serra, M.; Salagre, P.; Cesteros, Y.; Medina, F.; Sueiras, J.E. J. Catal. 2002, 209,202.
[18] Mikhailenko, S. D.; Khodareva, T. A.; Leongardt, E. V.; Lyashenko, A. I.; Fasman, A. B. J. Catal. 1993, 141,688.
[19] Wang, B.; Yang, L.-M.; Suo, J.-S. Acta Chim. Sinica 2003, 61, 285 (in Chinese).(王波,杨立明,索继栓,化学学报,2003,61,285.)
[20] Dai, W.-L.; Yu, H.-K.; Deng, J.-F.; Jiang, A.-R. ActaChim. Sinica 1995, 53, 188 (in Chinese).(戴维林,俞宏坤,邓景发,蒋安仁,化学学报,1995,53,188. )
[21] Drelinkiewicz, A. J. Mol. Catal. A 1995, 101, 61.
[22] Mikailenko, S. D.; Fasman, A. B.; Maksinova, N. A.; Leongard, E. V. Appl. Catal. 1984, 12, 141.

Mo对猝冷Ni-Mo骨架催化剂结构和催化性能的影响

Effect of Mo on the Structure and Catalytic Behavior of the Rapidly Quenched Skeletal Ni-Mo Catalysts

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 11

Recommended Articles

Metrics

Comments

[1]	Song Congying, Sun Xun, Ye Ke, Zhu Kai, Cheng Kui, Yan Jun, Cao Dianxue, Wang Guiling. Electrocatalytic Activity of MnO₂ Supported on Reduced Graphene Oxide Modified Ni Foam for H₂O₂ Reduction [J]. Acta Chim. Sinica, 2017, 75(10): 1003-1009.
[2]	Wang Dabin, Zhao Lixia, Guo Lianghong, Zhang Hui, Wan Bin, Yang Yu. Online Quantification of O₂^·- and H₂O₂ and Their Formation Kinetics in Ultraviolet (UV)-Irradiated Nano-TiO₂ Suspensions by Continuous Flow Chemiluminescence [J]. Acta Chim. Sinica, 2015, 73(5): 388-394.
[3]	Song Xiaojie, Wu Bingdang, Zhang Shujuan. Decoloration of Alizarin Red (an Anthraquinone Dye) with the UV/Acetylacetone Process [J]. Acta Chimica Sinica, 2014, 72(4): 461-466.
[4]	LV Yan-Zhuo, XU Yan, WANG Xue-Xin, ZHANG Yi, LU Tian-Hong. The Electrochemical Performances of Mg-8Li, Mg-8Li-0.5Ce and Mg-8Li-1Ce Alloys in 0.7 mol•L^－1 NaCl Solution [J]. Acta Chimica Sinica, 2011, 69(19): 2248-2252.
[5]	YANG Shao-Ming, HUANG Ai-Hua, CHA Wen-Ling, WEI Zhi-Peng, ZHENG Long-Zhen. H₂O₂ Biosensor Based on Poly(thionine) and Layer-by-Layer Self-assembly of Carbon Nanotubes and HRP [J]. Acta Chimica Sinica, 2011, 69(18): 2143-2147.
[6]	LIU Gao-Fu, KONG Fan-Juan, RAO Yan-Yang, DONG Jian, JIAN Wei-Beng. Preparation of Ag@SiO₂ Nanoparticles and Their Application in the Detection of H₂O₂ [J]. Acta Chimica Sinica, 2010, 68(9): 865-869.
[7]	QI Bin*; CHAO Yu-Tao. Theoretical Study on the Mechanism and Kinetics of the Reaction of Criegee Radical CH₂O₂with H₂O [J]. Acta Chimica Sinica, 2007, 65(19): 2117-2123.
[8]	WU Zhao-Yang*, FAN Zhan-Huang, TANG You-Yun, SHEN Guo-Li, YU Ru-Qin. Synthesis and Application of Novel H₂O₂Fluorescent Probe Based on the Deprotection Mechanism [J]. Acta Chimica Sinica, 2006, 64(8): 738-742.
[9]	ZHOU Li-Hui, XIAN Yue-Zhong, ZHOU Yu-Yan, HU Jun, LIU Hong-Lai. Adsorption of Hemoglobin on Au-modified Mesoporous SBA-15 and Application in Electrocatalysis of H₂O₂ Solution [J]. Acta Chimica Sinica, 2005, 63(23): 2117-2120.
[10]	LI Wen-Ling,HE Kan-Kan,LI Ying,HOU Zi-Jie*. Total Synthesis of (±)-Shegansu B, Gnetuhainin F, (±)-Maackin A and (±)-Cassigarol E [J]. Acta Chimica Sinica, 2005, 63(17): 1607-1612.
[11]	XU Jian-Hua, DAI Wei-Lin, YANG Xin-Li, CAO Yong, FAN Kang-Nian. Novel MCM-41 Supported Niobium Acid for the Catalytic Oxidation of Cyclopentene to Glutaraldehyde [J]. Acta Chimica Sinica, 2004, 62(16): 1467-1471.