Study on the Bond Valence Parameters for Tungsten-oxygen Bonds

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (18): 1733-1737. Previous Articles Next Articles

钨氧键价参数的研究

洪麒明, 周朝晖, 胡盛志

厦门大学化学系, 物理化学研究所, 固体表面物理化学国家重点实验室, 厦门, 361005

投稿日期:2004-04-04 修回日期:2004-05-31 发布日期:2014-02-17
通讯作者: 胡盛志,E-mail:szhu@xmu.edu.cn E-mail:szhu@xmu.edu.cn
基金资助:
国家重点基础研究发展规划(No.001CBl08906)资助项目.

Study on the Bond Valence Parameters for Tungsten-oxygen Bonds

HONG Qi-Ming, ZHOU Zhao-Hui, HU Sheng-Zhi

Department of Chemistry, Institute of Physical Chemistry and State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005

Received:2004-04-04 Revised:2004-05-31 Published:2014-02-17

Abstract

Based on the equation s_ij=exp[(R₀-r_ij)/B] of bond valence approach and 329 W—O bond length data in literature, linear equations of bond valence parameter R₀ with oxidation state n in different B for W—O bonds were established. The new bond valence parameters R₀=0.1896 nm and B=0.028 nm independent of n were also derived. The parameters fitted in this work were proved to be more suitable for the bond valence calculations. Applications of these parameters to some examples were illustrated.

Key words: bond valence parameter, W—O bond, oxidation state, bond valence sum

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HONG Qi-Ming, ZHOU Zhao-Hui, HU Sheng-Zhi. Study on the Bond Valence Parameters for Tungsten-oxygen Bonds[J]. Acta Chimica Sinica, 2004, 62(18): 1733-1737.

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钨氧键价参数的研究

Study on the Bond Valence Parameters for Tungsten-oxygen Bonds

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