Pure Ti-based Mixed Oxides Prepared from the Thermal Decompositions of Molecular Precursors of Peroxo Complexes Coordinated with Tris(hydroxycarbonylmethyl)amine Trivalent Anion Titanate(Ⅳ)

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (24): 2379-2385. Previous Articles Next Articles

过氧氨三乙酸钛配合物分子前体热分解制备纯钛基复氧化物

周朝晖, 洪麒明, 邓远富

厦门大学化学系, 固体表面物理化学国家重点实验室, 厦门, 361005

投稿日期:2004-04-15 修回日期:2004-06-28 发布日期:2014-02-17
通讯作者: 周朝晖,E-mail:zhzhou@xmu.edu.cn E-mail:zhzhou@xmu.edu.cn
基金资助:
国家重点基础研究发展规划(No.001CB108906)和国家自然科学基金(No.20021002)资助项目.

Pure Ti-based Mixed Oxides Prepared from the Thermal Decompositions of Molecular Precursors of Peroxo Complexes Coordinated with Tris(hydroxycarbonylmethyl)amine Trivalent Anion Titanate(Ⅳ)

ZHOU Zhao-Hui, HONG Qi-Ming, DENG Yuan-Fu

Department of Chemistry, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005

Received:2004-04-15 Revised:2004-06-28 Published:2014-02-17

Abstract

Different peroxo titanate(Ⅳ) complexes coordinated with tris(hydroxycarbonylmethyl)amine trivalent anion including ammonium, potassium, strontium and barium salts (NH₄)₄[Ti₂O(O₂)₂(ta)₂]·4H₂O (1), K₄[Ti₂O(O₂)₂(ta)₂]·6H₂O (2), Sr₂[Ti₂O(O₂)₂(ta)₂]·10H₂O (3) and Ba₂[Ti₂O(O₂)₂(ta)₂]·10H₂O (4) were obtained directly from the triad system of TiCl₄-H₂O₂-H₃ta [H₃ta=tris(hydroxycarbonylmethyl)amine] in pH 2.5～4.0. These complexes were characterized with elemental analysis, UV-vis and IR spectra. X-ray structural analysis shows that all complexes contain a similar dimeric anion structure, in which titanium atom is coordinated heptagonally by a peroxo group, a tetradenatate tris(hydroxycarbonylmethyl)amine trivalent anion ligand and a bridging oxygen atom. The cation Sr²⁺ and Ba²⁺ are coordinated enneahedrally and decagonally by water molecules and carboxyl groups of tris-(hydroxycarbonylmethyl)amine trivalent anion ligand respectively. The ammonium, strontium and barium salts can be decomposed stoichiometrically into the expected low-temperature phases of rutile TiO₂, SrTiO₃ and tetragonal BaTiO₃ at the temperature of 600℃ respectively, which has been confirmed by XRD characterization.

Key words: titanate, precursor, thermal decomposition, peroxo tris(hydroxycarbonylmethyl)amine

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ZHOU Zhao-Hui, HONG Qi-Ming, DENG Yuan-Fu. Pure Ti-based Mixed Oxides Prepared from the Thermal Decompositions of Molecular Precursors of Peroxo Complexes Coordinated with Tris(hydroxycarbonylmethyl)amine Trivalent Anion Titanate(Ⅳ)[J]. Acta Chimica Sinica, 2004, 62(24): 2379-2385.

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过氧氨三乙酸钛配合物分子前体热分解制备纯钛基复氧化物

Pure Ti-based Mixed Oxides Prepared from the Thermal Decompositions of Molecular Precursors of Peroxo Complexes Coordinated with Tris(hydroxycarbonylmethyl)amine Trivalent Anion Titanate(Ⅳ)

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