New Polymerizations Based on Green Monomer of Carbon Dioxide

doi:10.6023/A19090340

Acta Chimica Sinica ›› 2020, Vol. 78 ›› Issue (1): 9-22.DOI: 10.6023/A19090340 Previous Articles Next Articles

Review

绿色单体二氧化碳参与的新型聚合反应

宋波^a, 秦安军^a, 唐本忠^a,b

a 华南理工大学发光材料与器件国家重点实验室广东省分子聚集发光重点实验室聚集诱导发光研究中心广州 510640;
b 香港科技大学化学系国家人体组织功能重建工程技术研究中心香港分中心香港

投稿日期:2019-09-15 发布日期:2019-10-31
通讯作者: 秦安军, 唐本忠 E-mail:msqinaj@scut.edu.cn;tangbenz@ust.hk
作者简介:宋波,1993年出生于山西临汾,2015年在华南理工大学获得学士学位,2015~2019年在唐本忠院士和秦安军教授指导下开展博士阶段工作,于2019年6月获得华南理工大学博士学位.现为华南理工大学博士后.研究兴趣是探索CO₂和炔类单体的新型聚合反应,并探索CO₂基聚合物的功能化应用;秦安军,1999年和2004年分别在山西大学和中国科学院化学研究所取得学士和博士学位.2005至2008年先后在香港科技大学化学系和浙江大学高分子科学与工程学系从事博士后研究,合作导师均为唐本忠院士.出站后留校任教并于2008年12月晋升副教授,2013年9月至今任华南理工大学教授、博导.研究兴趣为基于三键单体的高分子合成化学以及有机/聚合物功能材料的制备和应用.发表学术论文280余篇,他引6600余次,h指数为56.2019年入选国家"万人计划"科技创新领军人才;2018年入选科技部"创新人才推进计划"中青年科技创新领军人才;2017年获国家自然科学奖一等奖(第二完成人),并入选英国皇家化学会Fellow;2015年获国家杰出青年科学基金资助,并入选国家"万人计划"青年拔尖人才支持计划;2012年获国家自然科学基金优秀青年科学基金资助;唐本忠,华南理工大学-香港科技大学联合研究院院长,香港科技大学张鉴泉理学教授,化学系与生物医学工程系讲座教授.1982年于华南理工大学获学士学位,1985年、1988年先后获日本京都大学硕士、博士学位;曾在多伦多大学化学与药学系从事博士后研究、日本NEOS公司中央研究所任高级研究员;1994年至今历任香港科技大学化学系助理教授、副教授、教授、讲座教授、张鉴泉理学教授;2009年当选中国科学院院士;2013年入选英国皇家化学会Fellow;2012年起受聘为华南理工大学兼职教授;2012年至今担任华南理工大学-香港科技大学联合实验室主任;2015年至今担任国家工程技术研究中心香港分中心主任.现为国家自然科学基金基础科学研究中心项目负责人,华南理工大学发光材料与器件国家重点实验室学术委员会主任,以及中国化学会和英国皇家化学会联合期刊Materials Chemistry Frontiers主编.唐本忠院士累计发表学术论文1400多篇,累计引用85000余次,h-指数为135,并于2014~2018年连续入选化学和材料双领域高被引用科学家.同时,唐本忠教授先后获得多项荣誉及奖励,如国家自然科学一等奖(2017,第一完成人)、何梁何利科学与技术进步奖(2017)、国家自然科学二等奖(2007,第四完成人)、裘槎高级研究成就奖(2007)、中国化学会高分子基础研究王葆仁奖(2007)和爱思唯尔出版社冯新德聚合物奖(2007)等.
基金资助:
项目受国家自然科学基金（Nos.21788102，21525417，21490571）、广东省自然科学基金（Nos.2016A030312002，2019B030301003）和香港创新及科技基金（ITC-CNERC14S01）资助.

New Polymerizations Based on Green Monomer of Carbon Dioxide

Song Bo^a, Qin Anjun^a, Tang Ben Zhong^a,b

a State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates, Center for Aggregation-Induced Emission, South China University of Technology, Guangzhou 510640;
b Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, The Hong Kong University of Science & Technology, Hong Kong

Received:2019-09-15 Published:2019-10-31
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21788102, 21525417, 21490571), the Natural Science Foundation of Guangdong Province (Nos. 2016A030312002, 2019B030301003), and the Innovation and Technology Commission of Hong Kong (ITC-CNERC14S01).

Carbon dioxide (CO₂) is an abundant, inexpensive, non-toxic and renewable C1 resource, and it is also a kind of green monomer. The polymerizations based on CO₂ have been one of the hot research topics. The copolymerization of CO₂ and epoxide monomers was widely studied in the past few years and has been industrialized. Some new polymerizations based on CO₂ have also been reported recently. There are two ways to produce polymeric materials from CO₂. One is converting CO₂ into monomers for further ring opening or step growth polymerizations, such as lactone, cyclic carbonates, furan-2,5-dicarboxylic acid. Another is directly using CO₂ as a monomer for the copolymerization with other monomers to generate polymers. They are both significant for developing new polymerizations based on CO₂ and expanding CO₂-based polymeric materials. The advances in converting CO₂ into polymeric materials during the past few years are summarized in this review and the perspective in this area is discussed.

Key words: carbon dioxide, alkyne monomer, cyclic carbonate, lactone, furan-2,5-dicarboxylic acid

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Song Bo, Qin Anjun, Tang Ben Zhong. New Polymerizations Based on Green Monomer of Carbon Dioxide[J]. Acta Chimica Sinica, 2020, 78(1): 9-22.

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绿色单体二氧化碳参与的新型聚合反应

New Polymerizations Based on Green Monomer of Carbon Dioxide

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