Research Progress of Transuranic Organometallic Chemistry

doi:10.6023/A23050212

Acta Chimica Sinica ›› 2023, Vol. 81 ›› Issue (11): 1633-1641.DOI: 10.6023/A23050212 Previous Articles Next Articles

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超铀金属有机化学研究进展

赵政嘉^a^,^b, 刘康^b, 郭燕^b, 于吉攀^b^,^*(), 石伟群^a^,^b^,^*()

a 南华大学核科学与技术学院衡阳 421001
b 中国科学院高能物理研究所核能化学实验室北京 100049

投稿日期:2023-05-07 发布日期:2023-07-17

作者简介:

赵政嘉, 2019年6月毕业于辽宁师范大学化学化工学院, 获理学学士学位; 2022年获辽宁师范大学有机化学专业硕士学位; 2022年9月至今为南华大学和中国科学院高能物理研究所联合培养博士研究生.

刘康, 2016年6月毕业于湖北大学化学化工学院, 获理学学士学位; 2021年12月毕业于中国科学院高能物理研究所, 获理学博士学位; 2022年1月至今于中国科学院高能物理研究所进行博士后研究. 目前主要研究方向为低价锕系化学.

郭燕, 博士, 讲师. 2008年获宁夏大学学士学位; 2012年获宁夏大学硕士学位; 2020年获西北大学博士学位; 2020年9月加入宁夏大学化学化工学院从事教学科研工作; 2022年2月至今在中国科学院高能物理研究所从事博士后研究. 目前主要研究方向为低价金属配合物的合成及磁性研究.

于吉攀, 副研究员. 2008年获江苏师范大学学士学位; 2011年获南开大学硕士学位; 2014年获清华大学博士学位; 2014年7月至2016年7月于清华大学化学系进行博士后研究; 2016年7月加入中国科学院高能物理研究所核能放射化学实验室; 目前主要研究方向为锕系元素化学.

石伟群, 研究员, 国家杰出青年科学基金获得者, 长期致力于核燃料循环化学与锕系元素化学相关基础研究, 在J. Am. Chem. Soc.、Angew. Chem.、Chem、CCS Chem.、Nat. Commun.、Adv. Mater.、Environ. Sci. Technol.等国际知名期刊发表SCI论文300余篇, 成果被国内外同行广泛关注和引用, 文章总引1万余次, H因子55 (Google Scholar). 分别担任期刊《Chinese Chemical Letters》、《Journal of Nuclear Fuel Cycle and Waste Technology》和《Journal of Nuclear Science and Technology》的编委与国际顾问编委, 中文期刊《核化学与放射化学》编委. 现为中国化学会核化学与放射化学专业委员会委员、中国核学会锕系物理与化学分会副理事长、中国有色金属学会熔盐化学与技术专业委员会副主任委员及中国核学会核化工分会理事兼副秘书长.

基金资助:
国家自然科学基金(22176191); 国家自然科学基金(21925603)

Research Progress of Transuranic Organometallic Chemistry

Zhengjia Zhao^a^,^b, Kang Liu^b, Yan Guo^b, Jipan Yu^b(), Weiqun Shi^a^,^b()

a School of Nuclear Science and Technology, University of South China, Hengyang 421001
b Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049

Received:2023-05-07 Published:2023-07-17
Contact: *E-mail: yujipan@ihep.ac.cn; shiwq@ihep.ac.cn
Supported by:
National Natural Science Foundation of China(22176191); National Natural Science Foundation of China(21925603)

Actinide organometallic compounds have attracted much attention due to their unique electronic structure and bonding properties. Due to the high toxicity and radioactivity of actinide, especially supersensitive to water and oxygen, the synthesis conditions and characterization methods of actinide organometallic compounds are harsh. In particular, transuranic elements are difficult to obtain, the research on transuranic organometallic chemistry is rarely reported due to the high level of radioactivity. In recent years, with the rapid development of synthesis and characterization techniques, some transuranic organometallic compounds with novel structures have been synthesized. The research on their electronic structure, bonding mode and physicochemical properties has further deepened the knowledge and understanding of transuranic elements. The recent studies on the synthesis and bonding properties of transuranic organometallic compounds are reviewed, which will provide guidance for the systematic understanding of the electronic structure and bonding rules of transuranic elements and the synthesis of novel structures of transuranic organometallic complexes.

Key words: transuranic element, radioactivity, organometallic compound, electronic structure, bonding nature

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Zhengjia Zhao, Kang Liu, Yan Guo, Jipan Yu, Weiqun Shi. Research Progress of Transuranic Organometallic Chemistry[J]. Acta Chimica Sinica, 2023, 81(11): 1633-1641.

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Fig. & Tab. 5

Scheme 1. Synthesis of neptunium organometallic compounds by radiochemistry

Scheme 2. Synthesis of [(TrenTIPS)NpCl] and [(TrenTIPS)NpO] complexes

Scheme 3. Study on the synthesis Np(III) complex and its reactivity

Scheme 4. Synthesis of neptunium organometallic compounds

Scheme 5. Study on the synthesis of plutonium organometallic compounds and their reactivities

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超铀金属有机化学研究进展

Research Progress of Transuranic Organometallic Chemistry

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